Synthesis, molecular structure, spectroscopic and computational studies on 4-(2-(2-(2-formylphenoxy)ethoxy)ethoxy)phthalonitrile as Functionalized Phthalonitrile

Authors

  • Pinar Sen Uskudar University
  • Salih Zeki Yıldız Sakarya University
  • Vildan Enisoglu Atalay Uskudar University
  • Sibel Demir Kanmazalp Gaziantep University, Gebze Technical University
  • Necmi Dege Ondokuz Mayıs University

DOI:

https://doi.org/10.20450/mjcce.2019.1495

Keywords:

Synthesis, Single crystal, Crystal structure, , aldehyde, phthalonitrile, theoretical calculation, DFT, HOMO and LUMO, NMR, Molecular description

Abstract

This work presents the synthesis and characterization of a novel compound, 4-(2-(2-(2-formylphenoxy)ethoxy)ethoxy)phthalonitrile as the aldehyde functional group substituted phthalonitrile derivative. The spectroscopic properties of the compound were examined by FT-IR, 1H-NMR, 13C-NMR, UV-vis, MS, elemental analyses. The molecular structure of the compound was also confirmed using X-ray single-crystal data with a theorical comparative approach.

Author Biographies

Pinar Sen, Uskudar University

Faculty of Engineering and Natural Sciences, Department of Forensic Science

Salih Zeki Yıldız, Sakarya University

Faculty of Arts and Sciences, Department of Chemistry

Vildan Enisoglu Atalay, Uskudar University

Faculty of Engineering and Natural Sciences, Department of Bioengineering

Sibel Demir Kanmazalp, Gaziantep University, Gebze Technical University

Physics Department

Necmi Dege, Ondokuz Mayıs University

Faculty of Arts and Sciences, Department of Physics

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Published

2019-05-24

How to Cite

Sen, P., Yıldız, S. Z., Atalay, V. E., Kanmazalp, S. D., & Dege, N. (2019). Synthesis, molecular structure, spectroscopic and computational studies on 4-(2-(2-(2-formylphenoxy)ethoxy)ethoxy)phthalonitrile as Functionalized Phthalonitrile. Macedonian Journal of Chemistry and Chemical Engineering, 38(1), 63–74. https://doi.org/10.20450/mjcce.2019.1495

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Section

Structural Chemistry