Multivariate factor assessment for lithogenic and anthropogenic distribution of macro and trace elements in surface water. Case study: Basin of the Bregalnica river, Republic of Macedonia

Trajce Stafilov, Biljana Balabanova, Robert Sajn, Claudiu Tánáselia

Abstract


This study presents the spatial distribution of 69 elements in the surface water of the Bregalnica river basin. The concentration of elements was determined using inductively coupled plasma with mass spectrometry (ICP-MS) and inductively coupled plasma - atomic emission spectrometry (ICP-AES). The data summary results were reduced with the application of multivariate factor analysis, whereupon three dominant geochemical associations were obtained: F1 (Ca-K-Mg-Na-Ba-Li-Mn-Sr-V), F2 (Al-Fe) and F3 (Sb). Anthropogenic enrichments of Pb and Zn occur in the Pb-Zn mine area. The obtained data exceeded the maximum allowed concentrations in accordance with the national regulation for surface water quality. Trace elements including REEs were significantly correlated with the dominant geological formations characteristic of the different sub-regions in the investigated area.


Keywords


water, heavy metals, factor analysis, spatial distribution, ICP-AES, ICP-MS, river Bregalnica

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References


G. W. Van Loon, S. J. Duffy, Environmental Chemistry: A global perspective, Oxford University Press, New York, 2000.

Y. Yi, Z. Yang, S. Zhang, Ecological risk assessment of heavy metals in sediment and human health risk assess-ment of heavy metals in fishes in the middle and lower reaches of the Yangtze river basin, Environ. Pollut., 159, 2575–2585 (2011).

V. Furtula, H. Osachoff, G. Derksen, H. Juahir, A. Colodey, P. Chambers, Inorganic nitrogen, sterols and bacterial source tracking as tools to characterize water quality and possible contamination sources in surface water, Water Res., 46, 1079–1092 (2012).

R. I. S. Alves, C. F. Sampaio, M, Nadal, M. Schuhmacher, J. L. Domingo, S. I. Segura-Muñoz, Metal concentrations in surface water and sediments from Pardo River, Brazil: Human health risks, Environ. Res., 133, 149–155 (2014).

J. Gaillardet, J. Viers, B. Dupre, Trace elements in river waters. In: J. I Dreaver, H. D. Holland, K. K. Turekian (Eds.), Treatise on Geochemistry. Surface and Ground-water Weathering and Soils, Elsevier-Pergamon, Oxford 2003, pp. 225–272.

H. E. Taylor, R. C. Antweiler, D. A. Roth, C. N. Alpers, P. Dileanis, Selected trace elements in the Sacramento River, California: occurrence and distribution, Archiv. Environ. Contam. Toxicol., 62, 557–569 (2012). [7] K. G. Bhattacharyya, N. Kapil, Impact of urbanization on the quality of water in a natural reservoir: a case study with the Deepor Beel in Guwahati City, India, Water Environ. J., 24, 83–96 (2010). [8] J. Das, Geochemistry of trace elements in the ground water of Cuttack City, India, Water Air Soil Pollut., 14, 129-140 (2003).

N. Haloi, H. Sarma, Heavy metal contaminations in the groundwater of Brahmaputra flood plain: an assessment of water quality in Barpeta District, Assam (India), En-viron. Monit. Assess., 184, 6229–6237 (2012).

S. Li, Q. Zhang, Risk assessment and seasonal variations of dissolved trace elements and heavy metals in the Up-per Han River, China, J. Hazardous Materials, 181, 1051–1058 (2010).

S. Su, R. Xiao, X. Mi, X. Xu, Z. Zhang, J. Wu, Spatial determinants of hazardous chemicals in surface water of Qiantang River, China, Ecol. Indic., 24, 375–381 (2013).

H. E. Taylor, 2001, Inductively Coupled Plasma - Mass Spectrometry: Practices and Techniques, Academic Press, New York, 2001.

T. Stafilov, R. Šajn, Z. Pančevski, B. Boev, M. V. Fron-tasyeva, L. Strelkova, Geochemical Atlas of Veles and the Environs, Faculty of Natural Sciences and Mathe-matics, Skopje, 2008.

T. Stafilov, R. Šajn, B. Boev, J. Cvetković, D. Mukae-tov, M. Andreevski, Geochemical Atlas of Kavadarci and the Environs, Faculty of Natural Sciences and Mathematics, Skopje, 2008.

T. Stafilov, B. Balabanova, R. Šajn, K. Bačeva, B. Boev. Geochemical Atlas of Radoviš and the Environs and the Distribution of Heavy Metals in the Air, Faculty of Natu-ral Sciences and Mathematics, Skopje, 2010.

T. Stafilov, R. Šajn, F. Sulejmani, K. Bačeva, Geo-chemical Atlas of Kičevo and the Environs, Faculty of Natural Sciences and Mathematics, Skopje, 2011.

T. Stafilov, B. Balabanova, R. Šajn, Geochemical Atlas of the Region of the Bregalnica River Basin, Faculty of Natural Sciences and Mathematics, Skopje, 2014.

B. Balabanova, T. Stafilov, K. Bačeva, R. Šajn, Biomonitoring of atmospheric pollution with heavy metals in the copper mine vicinity located near Radovıš, Republic of Macedonia, J. Environ. Sci. Health, Part A, 45, 1504–1518 (2010).

B. Balabanova, T. Stafilov, R. Šajn, K. Bačeva, Distri-bution of chemical elements in attic dust as reflection of lithology and anthropogenic influence in the vicinity of copper mine and flotation, Arch. Environ. Contam. Toxicol., 61, 173–184 (2011).

B. Balabanova, T. Stafilov, R. Šajn, K. Bačeva, Characterisation of heavy metals in lichen species Hypogymnia physodes and Evernia prunastri due to biomonitoring of air pollution in the vicinity of copper mine, Inter. J. Environ. Res., 6, 779–794 (2012).

B. Balabanova, T. Stafilov, R. Šajn, K. Bačeva, Spatial distribution and characterization of some toxic metals and lithogenic elements in top soil and subsoil from copper mine environs, Inter. J. Environ. Protec., 3, 1–9 (2013).

S. Ilič-Popov, T. Stafilov, R. Šajn, C. Tǎnǎselia, K. Bačeva, Applying of factor analyses for determination of trace elements distribution in water from River Vardar and its tributaries, Macedonia/Greece, Scientific World Journal, 2014, 1–11 (2014).

T. Stafilov, Environmental pollution with heavy metals in the Republic of Macedonia, Contributions, Section of Natural, Mathematical and Biotechnical Sciences, MASA, 35, 81–119 (2014).

A. Lazarevski, Climate in Macedonia, Kultura, Skopje, 1993

ISO 5667-4:1987 Water quality – Sampling – Part 4: Guidance on sampling from lakes, natural and man-made, International Organization for Standardization, Geneva, Switzerland.

G. E. P. Box, D. R. Cox, An analysis of transformations, J. R. Soc. Series B Stat. Methodol., 26(2), 211–252 (1964).

G. A. F. Seber, Multivariate observation, John Wiley & Sons Inc., Hoboken, New Jersey, 2008.

G. Žibret, R. Šajn, Hunting for geochemical associations of elements: factor analysis and self-organizing maps, Math. Geosci., 42, 681–703 (2010).

N. Dumurdžanov, T. Serafimovski, B. C. Burchfiel, Evolution of the Neogene-Pleistocene basins of Mace-donia. Geological Society of America, Digital Map and Chart Series 1, 2004.

Т. Rakićević, N. Dumurdžanov, М. Petkovski, Basic Geological Map of SFRJ, sheet Štip, M 1:100,000 (map & interpreter), Federal Geological Survey, Belgrade, 1968.

Official Gazette of the Republic of Macedonia, Regula-tion on classification of waters in the Republic of Mace-donia, No. 118, Skopje, 1999.

C. Abesser, R. Robinson, Mobilisation of iron and man-ganese from sediments of a Scottish upland reservoir, J. Limnol., 69, 42–53 (2010).

R. C. Antweiler, H. E. Taylor, C. N. Alpers, Distribution and geochemistry of selected trace elements in the Sac-ramento River near Keswick Reservoir, Chemical Geol-ogy, 298–299, 70–78 (2012).

J. J. Corbi, S. Trivinho-Strixino, A. Dos Santos, Envi-ronmental evaluation of metals in sediments and dragon-flies due to sugar cane cultivation in neotropical streams, Water Air Soil Pollut., 195, 325–333 (2008).

V. Bhardwaj, D. S. Singh, A. K. Singh, Environmental repercussions of cane-sugar industries on the Chhoti Gandak river basin, Ganga Plain, India, Environ. Monit. Assess., 171, 321–344 (2010).

T. Serafimovski, V. Stefanova, A. V. Volkova, Dwarf copper-gold porphyry deposits of the Buchim-Damjan Borov Dol ore district, Republic of Macedonia (FYROM), Geol. Ore Deposit., 52, 179–195 (2010). [37] St. Lehmann, J. Barcikowski, A. von Quadt, D. Gallhofer, I. Peytcheva, C. A. Heinrich, T. Serafimovski, Geochro-nology, geochemistry and isotope tracing of the Oligocene magmatism of the Bučim–Damjan–Borov Dol ore district: Implications for timing, duration and source of the mag-matism, Lithos, 180–181, 216–233 (2013).

B. Balabanova, T. Stafilov, R. Šajn, Lithogenic distribution of rare earth elements in automorphic and alluvial soils from Bregalnica river basin, Maced. J. Chem. Chem. Eng., 34 (1), 201–212 (2015).




DOI: http://dx.doi.org/10.20450/mjcce.2016.899

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