Two-step Double-regenerative EC'EC''
Meaning of the symbols of defined parameters:
-kc,1 and kc2 are the rate constants of
first and second regenerative step, respectively
-Kchem1 and Kchem2 are dimensionless chemical (regenerative) parameters related to the first and second regenerative step, respectively
-K1 and K2 are dimensionless rate parameters related to the first and second electron transfer step, respectively
-ks1 and ks2 are standard rate constants of first and second
electron transfer steps, respectively
-ΦI and ΦII are dimensionless potentials
-D is symbol for the diffusion coefficient (assumed to be identical
for all redox active species involved in the mechanism
-j is serial number of time increments
are numerical integration
parameters
-n is number of electrons exchanged
-dE is potential step
-Esw is square-wave amplitude
-f is SW frequency
-EsI and EsII are stadard potential of
first and second electron trasfer step
respectively
-α1 and α2 are electron transfer coefficients
related to the first and cesond electron transfer
step, respectively
-F, R and T are faraday constant, Gas constant
and temperautre, respectively
-potI and potII are potential modulations related to
the first and second electron transfer
step, respectively
-Ψ is symbol for the dimensionless current