Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities

Authors

  • Semih Gorduk Department of Chemistry, Faculity of Arts and Science, Yildiz Technical University, Istanbul http://orcid.org/0000-0001-7956-8368
  • Hakan Yilmaz Department of Chemistry, Faculty of Arts and Science, Ondokuz Mayıs University, Samsun
  • Omer Andac Department of Chemistry, Faculty of Arts and Science, Ondokuz Mayıs University, Samsun

DOI:

https://doi.org/10.20450/mjcce.2019.1711

Keywords:

Pyrazine-2, 3-dicarboxylato, 1-Vinylimidazole, Polymeric complex, Hydrogen storage, Bridging ligand

Abstract

In this study, two new coordination polymers of Cu(II) and Cd(II) ions with pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole were synthesized. The structures of these coordination polymers were characterized with elemental analysis, infrared spectroscopy, thermal analysis, powder X-ray diffraction, and magnetic susceptibility techniques. According to the results of the thermal analysis, the coordination polymers that contained water molecules decomposed below 100 °C, and the final products for both coordination polymers were the related metal oxides in an oxygen atmosphere. Powder X-ray diffraction analysis revealed that the coordination polymers were in the crystalline form. The hydrogen storage capacities and surface areas of the coordination polymers were also determined. The highest hydrogen storage capacities were measured as 296 ml/g for the Cu(II) coordination polymer and 330 ml/g for the Cd(II) coordination polymer at approximately 75 bar and 75 K.

Author Biographies

Semih Gorduk, Department of Chemistry, Faculity of Arts and Science, Yildiz Technical University, Istanbul

Dr. in Yildiz Technical University, Faculty of Arts and Science, Department of Chemistry

Hakan Yilmaz, Department of Chemistry, Faculty of Arts and Science, Ondokuz Mayıs University, Samsun

Dr. in Ondokuz Mayıs University, Faculty of Arts and Science, Department of Chemistry

Omer Andac, Department of Chemistry, Faculty of Arts and Science, Ondokuz Mayıs University, Samsun

Prof. Dr. in Ondokuz Mayıs University, Faculty of Arts and Science, Department of Chemistry

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Published

2019-05-21

How to Cite

Gorduk, S., Yilmaz, H., & Andac, O. (2019). Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities. Macedonian Journal of Chemistry and Chemical Engineering, 38(1), 19–27. https://doi.org/10.20450/mjcce.2019.1711

Issue

Vol. 38 No. 1 (2019)

Section

Inorganic Chemistry

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