Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate

Authors

  • Enrique J. Baran Universidad Nacional de La Plata
  • Beatriz S. Parajón-Costa Universidad Nacional de La Plata
  • Gustavo A. Echeverría Universidad Nacional de La Plata
  • Oscar E. Piro Universidad Nacional de La Plata

DOI:

https://doi.org/10.20450/mjcce.2015.630

Keywords:

thallium(I) acesulfamate, synthesis, crystal structure, IR spectra, Raman spectra

Abstract

SYNTHESIS, STRUCTURAL AND SPECTROSCOPIC CHARACTERIZATION OF THALLIUM(I) ACESULFAMATE

 

     The new acesulfamate salt, TlC4H4NO4S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution.  Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group P21/a, with unit cell parameters a = 7.5844(4) Å, b = 9.7268(5) Å, c = 10.8105(5) Å, β = 105.174(6)°, and Z=4 molecules per unit cell, and is isostructural with the corresponding sodium, potassium, rubidium and cesium salts. The FTIR and Raman spectra of the compound are also recorded and briefly discussed.

Author Biographies

Enrique J. Baran, Universidad Nacional de La Plata

Senior Researcher

Centro de Quimica Inorganica-CEQUINOR-

Facultad de Ciencias Exactas

Universidad Nacional de La Plata

LA PLATA/ARGENTINA

Beatriz S. Parajón-Costa, Universidad Nacional de La Plata

Researcher

Centro de Quimica Inorganica-CEQUINOR-

Gustavo A. Echeverría, Universidad Nacional de La Plata

Researcher

Departamento de Fisica, Facultad de Ciencias Exactas

Oscar E. Piro, Universidad Nacional de La Plata

Researcher

Departamento de Fisica, Facultad de Ciencias Exactas

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Published

2015-05-19

How to Cite

Baran, E. J., Parajón-Costa, B. S., Echeverría, G. A., & Piro, O. E. (2015). Synthesis, structural and spectroscopic characterization of thallium(I) acesulfamate. Macedonian Journal of Chemistry and Chemical Engineering, 34(1), 95–100. https://doi.org/10.20450/mjcce.2015.630

Issue

Vol. 34 No. 1 (2015)

Section

Inorganic Chemistry

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