Bis(N,N′-bis(2-hydroxyethyl)ethylenediamine)nickel(II) saccharinate: synthesis, characterization and crystal structure

Authors

  • Alparslan Karadogan Department of Chemistry, Faculty of Arts and Sciences, Gaziosmanpasa University, Tokat
  • Ahmet Karadag Department of Chemistry, Faculty of Arts and Sciences, Gaziosmanpasa University, Tokat
  • Veysel T. Yilmaz Uludag University

DOI:

https://doi.org/10.20450/mjcce.2015.651

Keywords:

Saccharinate, N, N′-bis(2-hydroxyethyl)ethylenediamine, nickel(II), crystal structure

Abstract

A new nickel(II) saccharinate (sac) complex containing N,N′-bis(2-hydroxyethyl)ethylenediamine (bishydeten), [Ni(bishydeten)2](sac)2, has been synthesized and characterized by elemental analysis, FTIR and single crystal X-ray diffraction. The title complex consists of a [Ni(bishydeten)2]2+ cation and two sac anions. In the complex cation, the nickel(II) ion is coordinated by two neutral bishydeten ligands, leading to a distorted octahedral NiN4O2 coordination, while both sac anions remain outside the coordination sphere. In the crystal, the complex cations and sac anions are connected by an extensive network of N–H∙∙∙N, N–H∙∙∙O, O–H∙∙∙O and C–H∙∙∙O hydrogen bonds into a three-dimensional supramolecular lattice.

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Published

2015-03-19

How to Cite

Karadogan, A., Karadag, A., & Yilmaz, V. T. (2015). Bis(N,N′-bis(2-hydroxyethyl)ethylenediamine)nickel(II) saccharinate: synthesis, characterization and crystal structure. Macedonian Journal of Chemistry and Chemical Engineering, 34(1), 101–104. https://doi.org/10.20450/mjcce.2015.651

Issue

Vol. 34 No. 1 (2015)

Section

Inorganic Chemistry

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