Study of corrosion inhibition for mild steel in NaCl solution by propolis extract

Veselinka Grudić, Ivana Bošković, Sanja Martinez, Bojana Knežević

Abstract


This paper studies the corrosion inhibition of X52 5L carbon steel in 0.51 mol dm-3 sodium chloride solution in the presence of propolis extract. The inhibition efficiency of propolis extract in a chloride solution was tested by its adding to the working solution and by making a solid propolis coating on the electrode surface. The possibility of corrosion inhibition in the presence of propolis in flow conditions as well as at different temperatures was investigated by electrochemical methods: potentiodynamic polarization method and electrochemical impedance spectroscopy. It was shown that propolis extract acts as a corrosion inhibitor of anodic type whose efficiency increases with increasing of temperature and with stirring of solution. The best protection is achieved by applying propolis coating in flow systems. The EIS method confirmed formation of a protective layer by adsorption of propolis extract on the electrode surface. The results of the FTIR, SEM and EDX surface tests are consistent with the results of electrochemical testing and suggest that propolis extract acts as a corrosion inhibitor of steel by forming a protective film on the electrode surface.


Keywords


carbon steel; propolis; corrosion; inhibition efficiency

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References


K. Barton, Protection Against Atmospheric Corrosion, John Wiley and Sons, New York, 1973, p. 32.

P. B. Raja, A. K.Qureshi, A. A.Rahim, H. Osman, K. Awang, Neolamarckia cadamba alkaloids as eco-friendly corrosion inhibitors for mild steel in 1 M HCl media, Corros. Sci. 69, 292-301 (2013), https://doi.org/10.1016/j.corsci.2012.11.042

M. A. Quraishi, A. Singh, V. K. Singh V, D. Y. Yadav, A. K. Singh, Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid solutions by the extract of Murraya koenigii leaves, Mater. Chem. Phys. 122(1), 114-122 (2010), https://doi.org/10.1016/j.matchemphys.2010.02.066

Y. Li, P. Zhao, Q. Liang, B. R. Hou, Berberine as a natural source inhibitor for mild steel in 1 M H2SO4, Appl. Surf. Sci. 252(5), 1245-1253 (2005), https://doi.org/10.1016/j.apsusc.2005.02.094

E. E. Oguzie, Corrosion inhibitive effect and adsorption behaviour of Hibiscus sabdariffa extract on mild steel in acidic media, Port. Electrochim. Acta 26 (3), 303-314 (2008),

A. Bouyanzer, B. Hammouti, A study of anti-corrosive effects of Artemisia oil on steel, Pigment & Resin Technology, 33(5), 287-292 (2004), https://doi.org/10.1108/0369942041056048/

N. O. Eddy, S. A. Odoemelam, A. O. Odiongenyi, Ethanol extract of musa species peels as a green corrosion inhibitor for mild steel: Kinetics, adsorption and thermodynamic considerations, Electron. J. Environ. Agric. Food Chem. 8(4) 243-245

(2009)

K. Anuradha, R. Vimala, B. Narayanasamy, J. Selvi, R. S. Arockia, Corrosion inhibition of carbon steel in low chloride media by an aqueous extract of hibiscus rosa-sinensis Linn, J. Chem. Eng. Commun. 195(3), 352-366 (2007), https://doi.org/10.1080/00986440701673283

I. Radojčić, K. Berković, S. Kovač, J. Vorkapić-Furac, Natural honey and blackradish juice as tin corrosion inhibitors, Corros. Sci. 50, 1498–1504 (2008), https://doi.org/10.1016/j.corsci.2008.01.013

W. B.Wan Nik, M. F. Zulkifli, R. Rosliza, M. J.Ghazali, K. F. Khaled, Potential of honey as corrosion inhibitor for aluminium alloy in seawater, World Appl. Sci. J. 14, 215–220 (2011),

A.Y. El-Etre, M. Abdallah, Natural honey as corrosion inhibitor for metals andalloys. II. C-steel in high saline water, Corros. Sci. 42(4), 731–738 (2000), https://doi.org/10.1016/S0010-938X(99)00106-7

A.O. Odiongenyi, I.S. Enengedi, I. Ibok, E.J. Ukpong, Inhibition of the corrosionof zinc in 0.1 M HCl by ethanol extract of honey, Int. J. Chem. Mater. Environ. Res. 2, 16–25 (2015),

R. Rosliza, W.B. Wan Nik, S. Izman, Y. Prawoto, Anti-corrosive properties ofnatural honey on Al-Mg-Si alloy in seawater, Curr. Appl. Phys. 10, 923–929 (2010), https://doi.org/10.1016/j.cap.2009.11.074

L. Vrsalović, S. Gudić, M. Kliskić, Salvia officinalis L. honey as corrosion inhibitor for CuNiFe in sodium chloride solution, Ind. J. Chem. Technol. 19, 96–102 (2012),

F. Gapsari, R. Soenoko, A. Suprapto, W. Suprapto, Bee wax propolis extract aseco-friendly corrosion inhibitors for 304SS in sulfuric acid, Int. J. Corros. 2015,1–10 (2015), http://dx.doi.org/10.1155/2015/567202

A.S. Fouda, A. Hamdy Badr, Aqueous extract of propolis as corrosion inhibitorfor carbon steel in aqueous solutions, Afr. J. Pure Appl. Chem. 7, 350–359 (2013), DOI : 10.5897/AJPAC2013.0524

L. M. P. Dolabella, J. G. Oliveira, V. Lins, T. Matencio, W. L. Vasconcelos, Ethanol extract of propolis as a protective coating for mild steel in chloride media, J.Coat. Technol. Res. 13, 543–555 (2016),

K.R. Markham, K.A. Mitchell, A.L. Wilkins, J.A. Daldy, Y. Lu, HPLC and GC–MS identification of the major organic constituents in New Zealand propolis, Phytochem. 42, 205–211 (1996), https://doi.org/10.1016/0031-9422(96)83286-9

R. Babolan, Corrosion tests and standards, Application and interpretation- second edition, ASTM International, USA, 2005

H. Otmačić- Ćurković, E. Stupnišek-Lisac, H. Takenouti, The influence of pH value on the efficiency of imidazole based corrosion inhibitors of copper, Corros. Sci. 52, 398 (2010) https://doi.org/10.1016/j.corsci.2009.09.026

A. Frignani, G. Trabanelli, F. Zucchi, and M. Zucchini, Proceedings of 5th European Symposium of Corrosion Inhibitors, Ferrara, Italy, 1980, p. 1185.

V. S. Sastri, Corrosion Inhibitors: Principles and Applications, J. Wiley, New York, 1998, p. 39.

S. M. A. Hosseini, M. Salari, E. Jamalizadeh, S. Khezripoor, M. Seifi, Inhibition of mild steel corrosion in sulfuric acid by some newly synthesized organic compounds, Mater. Chem. Phys.119, 100-105 (2010), https://doi.org/10.1016/j.matchemphys.2009.08.029

X. He, Y. Jiang, C. Li, W. Wang, B. Hou, L. Wu, Inhibition properties and adsorption behavior of imidazole and 2-phenyl-2-imidazoline on AA5052 in 1.0 M HCl solution, Corros. Sci. 83, 124–136 (2014), https://doi.org/10.1016/j.corsci.2014.02.004

M. Behpour, S.M. Ghoreishi, N. Soltani, M. Salavati-Niasari, M. Hamadanian, A.

Gandomi, Electrochemical and theoretical investigation on the corrosion inhibition of mild steel by thiosalicylaldehyde derivatives in hydrochloric acid solution, Corros. Sci. 50, 2172–2181 (2008), https://doi.org/10.1016/j.corsci.2008.06.020

X. Wang, Y. Wan, Y. Gu, Y. Ma, F. Shi, W. Nui, Q. Wang, Inhibition and adsorptive behavior of synthesized 1,4-bis (2-benzimidazolyl) benzene on mild steel in 3 M HCl solution, Int. J. Electrochem. Sci. 9, 1840–1853 (2014),

G.M. Schmid, H.J. Huang, Spectro-electrochemical studies of the inhibition effect of 4, 7-diphenyl -1, 10-phenanthroline on the corrosion of 304 stainless steel, Corros. Sci. 20, 1041-1057 (1980), https://doi.org/10.1016/0010-938X(80)90083-9

S. Andreani, M. Znini , J. Paolini, L. Majidi, B. Hammouti, J. Costa, A. Muselli, Study of Corrosion Inhibition for Mild Steel in Hydrochloric Acid Solution by Limbarda crithmoides (L.) Essential Oil of Corsica, J. Mater. Environ. Sci. 7 (1), 187-195 (2016),

D. Asefi, M.Arami, N.Mahmoodi, Electrochemical effect of cationic gemini surfactant and halide salts on corrosion inhibition of low carbon steel in acid medium, Corros. Sci. 52, 794-800 (2010), https://doi.org/10.1016/j.corsci.2009.10.039

S.Shukla, M.Quraishi, The effects of pharmaceutically active compound doxycycline on the corrosion of mild steel in hydrochloric acid solution, Corros. Sci. 52, 314-321 (2010), https://doi.org/10.1016/j.corsci.2009.09.017

H. Ashassi-Sorkhabi, N. Ghalebsaz-Jeddi, F. Hasemzadeh, H. Jahani, Corrosion inhibition of carbon steel in hydrochloric acid by some polyethylene glycols, Electrochim. Acta 51, 3848-3854 (2006), https://doi.org/10.1016/j.electacta.2005.11.002

K.F. Khaled, Corrosion control of copper in nitric acid solutions using some amino acids − a combined experimental and theoretical study, Corros. Sci. 52, 3225–3234 (2010), https://doi.org/10.1016/j.corsci.2010.05.039

S. Deng, X. Li, X. Xie, Hydroxymethyl urea and 1,3-bis(hydroxymethyl) urea as corrosion inhibitors for steel in HCl solution, Corros. Sci. 80, 276–289 (2014), https://doi.org/10.1016/j.corsci.2013.11.041

C. C. Li, X.Y. Guo, S. Shen, P. Song, T. Xu, Y. Wen, H.F. Yang, Adsorption and corrosion inhibition of phytic acid calcium on the copper surface in 3 wt.% NaCl solution, Corros. Sci. 83, 147–154 (2014), https://doi.org/10.1016/j.corsci.2014.02.001

D.K. Yadav, M.A. Quraishi, B. Maiti, Inhibition effect of some benzylidenes on mild steel in 1 M HCl: an experimental and theoretical correlation, Corros. Sci. 55, 254–266 (2012), https://doi.org/10.1016/j.corsci.2011.10.030

D. Wang, B. Xiang, Y. Liang, S. Song, C. Liu, Corrosion control of copper in 3.5 wt.% NaCl solution by Domperidone: experimental and theoretical study, Corros. Sci. 85, 77–86 (2014), https://doi.org/10.1016/j.corsci.2014.04.002

R. M. Cornell, U. Schwertmann, The Iron–Oxides – Structure, Properties, Reactions, Occurences and Uses, Springer, Berlin, 1996, p. 573

S. Hosseinpour, M. Johnson, Vibrational Spectroscopy in Studies of Atmospheric Corrosion, Materials 10(4), 413 (2017), https://doi.org/10.3390/ma10040413

R. Jasinski, A. Lob, FTIR Measurements of Iron Oxides on Low Alloy Steel, J. Electrochem. Soc.135(3), 551-556 (1988), doi 10.1149/1.2095656

R. I. Pramana, R. Kusumastuti, J.W. Soedarsono, A. Rustandi, Corrosion Inhibition of Low Carbon Steel by Pluchea Indica Less. in 3.5% NaCl Solution, Adv. Mater. Res. 785-786, 20-24 (2013), https://doi.org/10.4028/www.scientific.net/AMR.785-786.20

H. Hachelef, , A. Benmoussat, A. Khelifa, M. Meziane, Study of the propolis extract as a corrosion inhibitor of copper alloy in ethylene glycol/water 0.1 M NaCl, J. Fundam. App. Sci. 9(2), 650-668 (2017), http://dx.doi.org/10.4314/jfas.v9i2.3

R. N. Oliveira et al., FTIR analysis and quantification of phenols and flavonoids of five commercially available plants extracts used in wound healing, Matéria (RioJ.) 21(3), 767-779 (2016), http://dx.doi.org/10.1590/S1517-707620160003.0072




DOI: http://dx.doi.org/10.20450/mjcce.2018.1513

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Copyright (c) 2018 Veselinka Grudić, Ivana Bošković, Sanja Martinez, Bojana Knežević

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