Multi-element analysis of Macedonian wines by inductively coupled plasma–mass spectrometry (ICP–MS) and inductively coupled plasma–optical emission spectrometry (IP–OES) for regional classification

Authors

  • Violeta Ivanova-Petropulos Faculty of Agriculture, University Goce Delčev, Štip
  • Helmar Wiltsche Graz University of Technology, Institute of Analytical Chemistry and Food Chemistry, Graz
  • Trajče Stafilov Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University, Skopje
  • Marina Stefova Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University, Skopje
  • Herber Motter Graz University of Technology, Institute of Analytical Chemistry and Food Chemistry, Graz
  • Ernst Lankmayr Graz University of Technology, Institute of Analytical Chemistry and Food Chemistry, Graz

DOI:

https://doi.org/10.20450/mjcce.2013.447

Keywords:

elemental composition, red and white wines, multivariate analysis, ICP-MS, ICP-OES

Abstract

Major, minor, and trace elements in wines from the Republic of Macedonia were determined in this study. Both inductively coupled plasma–mass spectrometry (ICP-MS) and inductively coupled plasma– optical emission spectrometry (ICP-OES) were used for accurate determination of the concentration of 42 elements (Ag, Al, Au, B, Ba, Be, Bi, Ca, Cd, Ce, Co, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Ho, La, Lu, Mg, Mn, Mo, Na, Nd, Ni, P, Pb, Pr, S, Sm, Tb, Ti, Tl, Tm, U, V, Yb, Zn, Zr) in 25 Macedonian white, rose, and red wines from different wine regions. By means of factor and cluster analyses, the wines were discriminated according to wine type (white vs. red) and geographical origin. The main discriminant elements were B, Ba, Ca, Fe, Mg, Mn, P, and S.

 

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Published

2013-12-01

How to Cite

Ivanova-Petropulos, V., Wiltsche, H., Stafilov, T., Stefova, M., Motter, H., & Lankmayr, E. (2013). Multi-element analysis of Macedonian wines by inductively coupled plasma–mass spectrometry (ICP–MS) and inductively coupled plasma–optical emission spectrometry (IP–OES) for regional classification. Macedonian Journal of Chemistry and Chemical Engineering, 32(2), 265–281. https://doi.org/10.20450/mjcce.2013.447

Issue

Vol. 32 No. 2 (2013)

Section

Food Chemistry

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