Luminescence methods for study and determination of pollutants in the environment
DOI:
https://doi.org/10.20450/mjcce.2010.170Keywords:
luminescence, fluorescence, phosphorescence, bioluminescence, HPLC, CE, FIA, micellar media, cyclodextrins, pollutantsAbstract
The analytical performances and applications of various luminescence spectrometric methods to the study and determination of pollutants present at low levels in the environment are reviewed for the last two decades (1990 – 2010). The first part concerns luminescence stationary systems, including fluorescence, photochemically-induced fluorescence, phosphorescence and related luminescence methods. In the second part, the combination of these luminescence methods with flow techniques such as high performance liquid chromatography (HPLC), capillary electrophoresis (CE) and flow injection analysis (FIA) for the detection and determination of environmental pollutants is investigated. A part of the review is also devoted to the usefulness of organized supramolecular systems, such as micellar media, cyclodextrins and calixarenes, for improving the efficiency of luminescence methods.References
C. Baird, Environmental Chemistry, 2nd edition, W. H Freeman and Company, New York, 1999.
F. W. Fifield, P. J. Haines (Eds.), Environmental Analytical Chemistry, Blackie Academic & Professional, Chapman & Hall, London, 1997.
L. Baraud, D. Tessier, J.-J. Aaron, J.-P. Quisefit, J. Pinart, A multi-residue method for the characterization and determination of atmosphere pesticides measured at two French, urban and rural sampling sites, Anal. Bioanal. Chem., 377, 1148–1152 (2003).
M. Chevreuil, L’atmosphère, vecteur de micropolluants organiques aux écosystèmes, L’Actualité Chimique, 277–278, 40–48 (2004).
A. Nestorovska-Krsteska, M. Mirčeska, J.-J. Aaron, Z. Zdravkovski, Determination of dimethoate, 2,4- dichlorophenoxy acetic acid, mecoprop and linuron pesticides in environmental waters in R. Macedonia by high-performance liquid chromatography, Maced. J. Chem. Chem. Engin., 27, 25–33 (2008).
S. Irace-Guigand, J.-J. Aaron, P. Scribe, D. Barcelo, A comparison of the environmental impact of pesticide multi-residues and their occurrence in river waters surveyed by liquid chromatography coupled in tandem with UV diode array detection and mass spectrometry, Chemosphere, 55, 973–981 (2004).
S. G. Schulman (Ed.), Molecular Luminescence Spectroscopy. Methods and Applications, John Wiley and Sons, New York, Part 1, 1985; Part 2, 1988; Part 3, 1993.
M. C. Goldberg (Ed.), Luminescence Applications in Biological, Chemical, Environmental and Hydrological Sciences, American Chemical Society, Washington, 1989.
W. R. G. Baeyens, D. De Keukeleire, K. Korkidis (Eds.), Luminescence Techniques in Chemical and Biochemical Analysis, Marcel Dekker, New York, 1991.
G. Guilbault, Practical Fluorescence, Marcel Dekker, New York, 1990.
A. W. Czarnik (Ed.), Fluorescence Chemosensors for Ion and Molecule Recognition, American Chemical Society, Washington, 1992.
O. S. Wolfbeis (Ed.), Fluorescence Spectroscopy. New Methods and Applications, Springer-Verlag, Berlin, 1993.
B. Valeur, J. C. Brochon (Eds.), New Trends in Fluorescence Spectroscopy. Applications to Chemical and Life Sciences, Springer-Verlag, Berlin, 2001.
B. Valeur, Molecular Fluorescence. Principles and Applications, Wiley-VCH, Weinheim, 2002.
E. Pelizzetti, E. Pramauro, Analytical applications of organized molecular assemblies, Anal. Chim. Acta, 169, 1–29 (1985).
W. L. Hinze, H. N. Singh, Y. Baba, N. G. Harvey, Micellar enhanced fluorimetry, Trends Anal. Chem., 3, 193–199 (1984).
M. E. Díaz García, A. Sanz-Medel, Dye-surfactant interactions: a review, Talanta, 33, 255–264 (1986).
J. J. Santana Rodriguez, The role of organized media in chemiluminescence reactions, in: A. M. Garcia- Campana, W. R. G. Baeyens (Eds.) Chemiluminescence in Analytical Chemistry, Marcel Dekker, New York, 2001, pp. 285 – 319.
J. M. Lin, M. Yamada, Microheterogenous systems of micelles and microemulsions as reaction media in chemiluminescence analysis, Trends Anal. Chem., 22, 99–107 (2003).
W. L. Hinze, N. Srinivasan, T. K. Smith, S. Igarashi, H. Hoshino, in: I. M. Warner, L. B. McGown (Eds.), Advances in Multidimensional Luminescence, Vol. 1, JAI Press, Tokyo, 1991.
R. von Wandruzka, Luminescence of micellar solutions, Crit. Rev. Anal. Chem., 23, 187–215 (1992).
R. P. Frankewich, K. N. Thimmaiah, W. L. Hinze, Evaluation of the relative effectiveness of different water- soluble β-cyclodextrin media to function as fluorescence enhancement agents, Anal. Chem., 63, 2924–2933 (1991).
R. A. Femia, S. Scypinski, L. J. Cline Love, Fluorescence characteristics of polychlorinated biphenyl isomers in cyclodextrin media, Environ. Sci. Technol., 19, 155–159 (1985).
J. J. Santana Rodriguez, R. Halko, J. R. Betancort Rodriguez, J.-J. Aaron, Environmental analytical applications of luminescence in organized supramolecular systems, Anal. Bioanal. Chem., 385, 525–545 (2006).
E. Pramauro, E. Pelizzetti, in: S. G. Weber (Ed.), Surfactants in Analytical Chemistry. Applications of Organized Amphiphilic Media, Wilson and Wilson´s, Amsterdam (1996).
S. Rubio, A. Gomez-Hens, M. Valcarcel, Analytical applications of synchronous fluorescence spectrometry, Talanta, 33, 633–640 (1986).
J.-J. Aaron, Photochemical fluorometry, in: S. G. Schulman (Ed.), Molecular Luminescence Spectroscopy. Methods and Applications, Part 3. J. Wiley and Sons, New York, 1993, pp. 85–131.
J. J. Aaron, A. Coly, Luminescence methods in pesticide analysis. Applications to the environment, Analysis Eur. JAC, 28, 699–709 (2000).
M. C. Icardo, J. M. Calatayud, Photo-induced luminescence, Crit. Rev. Anal. Chem., 38, 118–130 (2008).
R. J. Hurtubise, Phosphorimetry. Theory, Instrumentation and Application, VCH, New York, 1990.
J. Kuijt, F. Ariese, U. H. T. Brinkman, C Gooijer, Room temperature phosphorescence as a tool in analytical chemistry, Anal. Chim. Acta, 488, 135–171 (2003).
S. A. Bortolato, J. A. Arancibia, G. M. Escandar, A novel application of nylon membranes to the luminescent determination of benzo
[a]pyrene at ultra trace levels in water samples, Anal. Chim. Acta, 613, 218–227 (2008).
J. F. Fernandez-Sanchez, A. Segura Carratero, C. Cruces- Blanco, A. Fernandez –Gutierrez, The development of solid-surface fluorescence characterization of polycyclic aromatic hydrocarbons for potential screening tests in environmental samples, Talanta, 60, 287–293 (2003).
A. H. Ackerman and R. J. Hurtubise, Methods for coating filter paper for solid-phase micro-extraction with luminescence detection and characterization of the coated filter paper by infrared spectrometry, Anal. Chim. Acta, 474, 77–89 (2002).
J. L. Whitcomb, A. J. Bystol, A. D. Campiglia, Timeresolved laser-induced fluorimetry for screening polycyclic aromatic hydrocarbons on solid-phase extraction membranes, Anal. Chim. Acta, 464, 261–272 (2002).
S. G. Dmitrienko, E. Ya. Gurariv, R. E. Nosov, Yu. A. Zolotov, Solid-phase extraction of polycyclic aromatic hydrocarbons from aqueous samples using polyurethane foams in connection with solid-matrix spectrofluorimetry, Anal. Lett., 34, 425–438 (2001).
O. A. Djachuk, T. I. Gubina, G. V. Melnikov, Adsorption preconcentration in the luminescence determination of polycyclic aromatic hydrocarbons, J. Anal. Chem., 64, 3–7 (2009).
O. A. Djachuk, A. V. Tkachenko, The luminescence of polycyclic aromatic hydrocarbons on modified cellulose by surface-active agent, Progress in Biomedical Optics and Imaging – Proceed. SPIE, 6791, Art N°67910P (2008).
S. Vázquez Troche, I. Marinez Bugallo, M. S. Garcia Falcón, M. A. Lage Yusty, J. Simal Lozano, Constantwavelength synchronous spectrofluorimetry for determination of benzo
[a]pyrene, benzo
[b]fluoranthene and benzo
[k]fluoranthene in presence of 16 EPA PAHs Deutsche Lebensmittel-Rundschau, 99, 96–101 (2003).
A. Andrade Eiroa, S. R. Huckins, E. Vásquez Blanco, P. López Mahia, S. Muniategui Lorenzo, D. Prada Rodriguez, Optimizing resolution in constant-energy synchronous spectrofluorimetry, Appl. Spectrosc., 54, 1534–1538 (2000).
Y. Yan, J.-G. Xu, Z.-G. Lin, Y.-B. Zhao, L.-T. Wang, G.-Z. Chen, Study on total luminescence spectra. Application to three-dimensional synchronous fluorescence spectrometry, Anal. Chim. Acta, 306, 307–312 (1995).
J. J. Santana Rodríguez, Z. Sosa Ferrera, A. Afonso Perera, V. González Diaz, Simultaneous synchronous fluorimetric determination of benzo
[a]pyrene and perylene in micellar media, Anal Chim Acta, 255, 107– 111(1991).
J. J. Santana Rodríguez, Z. Sosa Ferrera, A. Afonso Perera, V. González Diaz, Micellar, enhanced spectrofluorimetric determination of chlorophyll a and chlorophyll b in fresh waters Talanta, 39, 1611–1617 (1992).
J. J. Santana Rodríguez, J. Hernández García, M. M. Bernal, A. Bermejo Martín-Lázaro, Analysis of mixtures of polycyclic aromatic hydrocarbons in sea water by synchronous fluorescence spectrometry in organized, Analyst, 118, 917–921 (1993).
A. Bermejo Martín-Lázaro, J. Hernández García, J. J. Santana Rodríguez, Simultaneous determination of perylene and benzo
[ghi]-perylene by synchronous fluorescence using a micellar system, Fresenius J. Anal. Chem., 343, 509–512 (1992).
J. Guiteras, J. L. Beltrán, R. Ferrer, Quantitative multicomponent analysis of five polycyclic aromatic hydrocarbons in water samples, Anal Chim Acta, 361, 233– 240(1998).
D. Patra, A. K. Mishra, Investigation on simultaneous analysis of multicomponent polycyclic aromatic hydrocarbon mixtures in water samples: a simple synchronous fluorimetric method, Talanta , 55, 143–153 (2001).
J. Amador Hernández, P. L. López de Alba, A. Cladera, J. M. Estela, V. Cerdà, Resolution of a multicomponent polycyclic aromatic hydrocarbon system in micellar media by linear variable angle fluorescence applying distinct chemometric techniques, Analyst, 123, 2235–2242 (1998).
E. Lázaro, M. P. San Andrés, S. Vera, Determination of five polycyclic aromatic hydrocarbons in aqueous micellar media by fluorescence at room temperature, Anal Chim Acta, 413, 159–166 (2000).
S. Rubio Barroso, D. López López, C. Val Ontillera, L. M. Polo Díez, Estudio espectrofluorimetrico de PAHs en medios organizados de β-Ciclodextrina y Pluronic- F-68, Quim. Anal., 10, 127–136 (1991).
S. Rubio Barroso, M. N. Kayali, L. M. Polo Díez, Evaluation of some PAHs in particulate air by fluorimetry in ionic surfactants micellar solutions, Quim. Anal., 12, 187-191(1993).
S. Rubio Barroso, M. N. Kayali, L. M. Polo Díez, Fluorimetric study of polycyclic aromatic hydrocarbons in Brij-35 micellar solution. Evaluation of polycyclic aromatic hydrocarbons in air samples, Anal. Chim. Acta, 283, 304–308 (1993).
W. Jin, C. Liu, Luminescence rule of polycyclic aromatic hydrocarbons in micelle-stabilized roomtemperature phosphorescence, Anal. Chem., 65, 863- 865 (1993)
W. J. Jin, C. S. Liu, Study on Five Polycyclic Aromatic Hydrocarbons by Chemical Deoxygenation Micelle- Stabilized Room Temperature Phosphorimetry, Microchem. J., 48, 94–103 (1993).
M Algarra, M Hernández, Determination of fluorene in sea-water by room temperature phosphorescence in organised media, Analyst, 123, 2217–2219 (1998).
A. Segura, C. Cruces, M. Sánchez-Polo, J. C. Ávila- Rosón, A. Fernández, Study of different normalmicroemulsion composition by room-temperature phosphorescence to determine benzo
[a]pyrene in environmental samples, Anal. Chim. Acta, 474, 91–98 (2002).
S. Debnath, Q. Cheng, T. G. Heddermann, H. J. Byrne, A study of the interaction between single-walled carbon nanotubes and polycyclic aromatic hydrocarbons: Toward structure-property relationships, J. Phys. Chem. C, 112, 10418–10422 (2008).
H. Li, F. Qu, Selective inclusion of polycyclic aromatic hydrocarbons (PAHs) on calixarene coated silica nanospheres englobed with CdTe nanocrystals, J. Mater. Chem., 17, 3536–3544 (2007).
C. Gooijer, I. Kozin, N. H. Velthorst, Shpol'skii spectrometry, a distinct method in environmental analysis, Mikrochim. Acta, 127, 149–182 (1997).
I. Kozin, C. Gooijer, N. H. Velthorst, J. Hellou, V. Zitko, Isomer-specific detection of PAHs and PAH metabolites in environmental matrices by Shpol'skii luminescence spectroscopy, Chemosphere, 33, 1435–1447 (1996).
J. W. Hofstraat, U. P. Wild, Constant-Energy Synchronous Scan and Excitation Emission Matrix Shpol'skii Spectroscopy for Characterization of PAHs, J. Fluorescence, 8, 319–325 (1998).
L. Paturel, A.-I. Saber, C. Fachinger, J. Suptil, C. Turnar, A data acquisition and processing software for high-resolution Shpol'skii spectrofluorometry, Polycycl. Arom. Comp., 13, 151–164 (1999).
U. Kirso, N. Irha, L. Paalme, S. Reznikov, A. Matveyev, Levels and origin of PAHs in some big lakes, Polycycl. Arom. Comp., 22, 715–728 (2002).
I. Kozin, C. Gooijer, N. H. Velthorst, Shpol'skii spectroscopy as a tool in environmental analysis for aminoand nitro-substituted polycyclic aromatic hydrocarbons: A critical evaluation, Anal. Chim. Acta, 333, 193–204 (1996).
C. Plaza, B. Xing, J. M. Fernandez, N. Senesi, A. Polo, Binding of polycyclic aromatic hydrocarbons by humic acids formed during composting, Environ. Pollut., 157, 257–263 (2009).
S. B. Hawthorne, R. W. St Germain, N. A. Azzolina, Laser-induced fluorescence coupled with solid-phase microextraction for in situ determination of PAHs in sediment pore water, Environ. Sci, Technol., 42, 8021– 8026 (2008).
R. S. G. Gómez, T. Pandyan, V. E. A. Iris, V. Luna- Pabello, C. D. De Bazúa, Spectroscopic determination of poly-aromatic compounds in petroleum contaminated soils, Water, Air, Soil Pollut., 158, 137–151 (2004).
N. Hanson, Å. Larson, Fixed wavelength fluorescence to detect PAH metabolites in fish bile: Increased statistical power with an alternative dilution method, Environ. Monitor. Assessment, 144, 221–228 (2008).
A. S. Oliveira, M. B. Fernandez, J. C. Moreira, L. V. F. Ferreira, Ground-state diffuse reflectance and laserinduced luminescence on the evaluation of total PAHs in urban air particulate matter from Rio de Janeiro city in Brazil, J. Brazil. Chem. Soc., 13, 245–250 (2002).
J. Hernández García, Z. Sosa Ferrera, A. J. Bermejo Martín-Lázaro, J. J. Santana Rodríguez, Fluorimetric study of PCBs and Aroclors in micellar media. Analytical applications, Anal. Lett., 27, 1355–1382 (1994).
J. Hernández García, Z. Sosa Ferrera, A. J. Bermejo Martín-Lázaro, J. J. Santana Rodríguez, Fluorescent behaviour of polychlorinated dibenzofurans in organized molecular systems. Analytical applications, Mikrochim. Acta, 118, 185–196 (1995).
J. Hernández García, Z. Sosa Ferrera, A. J. Bermejo Martín-Lázaro, J. J. Santana Rodríguez, Determinacion espectrofluoremetrica de 2,8-diclorodibenzofurano usando un medio micelar de polioxietileno-10-laurileter (POLE), Quim. Anal., 13, 96–101 (1994).
J. Hernández García, J. R. Betancort Rodríguez, A. J. Bermejo Martín-Lázaro, J. J. Santana Rodríguez , Sensitive spectrofluorimetric determination of 3,3’,4,4’- tetrachlorobiphenyl using a neutral micellar medium, Anal. Chim. Acta, 290, 146–153 (1994).
J. J. Santana Rodríguez, J. Hernández García, Z. Sosa Ferrera, A. J. Bermejo Martín-Lázaro, Spectrofluorometric determination of 4-chlorobiphenyl and Arochlor 1221 using the fluorescence quenching produced by cetylpyridinium bromide micellar medium, Fresenius J. Anal. Chem., 354, 221–226 (1996).
J. J. Santana Rodríguez, Z. Sosa Ferrera, J. Hernández García, A. J. Bermejo Martín-Lázaro, Analysis of binary mixtures of 3,3',4,4'-tetrachlorobiphenyl and 2,3,7,8- tetrachlorodibenzofuran by derivative synchronous fluorescence spectrometry in organized media, Analyst, 119, 2241–2246 (1994).
J. P. Alarie, T. Vo-Dinh, G. Miller, M. N. Ericson, S. R. Maddox, W. Watts, D. Eastwood, R. Lidberg, M. Dominguez, Development of a battery-operated portable synchronous luminescence spectrofluorometer, Rev. Sci. Instrum., 64, 2541–2546 (1993).
G. J. Hyfantis Jr., W. Watts, T. P. Finnegan, Field applications of a portable luminoscope for hazardous screening, Proceed. SPIE-Intern. Soc. Opt. Engin., 3534, 92–99 (1999).
T. Vo-Dinh, A. Pal, T. Pat, Photoactivated luminescence method for rapid screening of polychlorinated biphenyls, Anal. Chem., 66, 1264–1268 (1994).
P. Jagasia, A. Velasquez, A. Knedlik, T. Vo-Dinh, P. B. Oldham, Enhanced photoactivated luminescence of selected polychlorinated biphenyl congeners and Aroclor mixtures, Microchem. J., 57, 350–360 (1997).
A. Pal, W. Watts, J. Caraway, T. Vo-Dinh, Enhanced room-temperature phosphorescence using sodium lauryl sulfate treated solid substrate, Analysis, 20, 149– 153(1992).
J. J. Santana Rodríguez, J. Hernández García, Z. Sosa Ferrera, A. Bermejo, Solid surface room-temperature phosphorescence of polychlorinated dibenzofurans enhanced by a surface active agent, Anal. Lett., 28, 2413– 2436 (1995).
J. C. Márquez, M. Hernández, F. García, Enhanced spectrofluorimetric determination of the pesticide warfarin by means of the inclusion complex with β-cyclodextrin, Analyst, 115, 1003–1005 (1990)
N. L. Pacioni, A. V. Veglia, Determination of carbaryl and carbofuran in fruits and tap water by β-cyclodextrin enhanced fluorimetric method, Anal. Chim. Acta, 488, 193–202 (2003).
J. H. Ayala, A. M. Afonso, V. González, Spectrofluorimetric determination of carbaryl and 1-naphthol in micellar media, Mikrochim. Acta, 1, 171–179 (1991).
R. M. Maggio, G. N. Piccirilli, G. M. Escandar, Fluorescence enhancement of carbendazim in the presence of cyclodextrins and micellar media: A reappraisal, Appl. Spectrosc., 59, 873–880 (2005).
S. Kunsági-Máté, G. Nagy, L. Kollár, Investigation of the interaction of calixarene (host) and neutral benzotrifluoride (guest) – Comparison of luminescence characteristics of calixarenes with results of model calculations relating to complex formation, Sensors and Actuators, B : Chem., 76, 545–550 (2001).
S. Kunsági-Máté, G. Nagy, L. Kollár, Host-guest interaction of calixarene molecules with neutral benzotrifluorides – Comparison of luminescence spectral data with results of model calculations relating to complex formation, Anal. Chim. Acta, 428, 301–307 (2001).
H. Li, F. Qu, Synthesis of CdTe quantum dots in solgel- derived composite silica spheres coated with calix
arene as luminescent probes for pesticides, Chem. Mater., 19, 4148–4154 (2007).
A. Coly, J. J. Aaron, Cyclodextrin-enhanced fluorescence and photochemically-induced fluorescence determination of five aromatic pesticides in water, Anal. Chim. Acta, 360, 129–141 (1998).
A. Coly, J. J. Aaron, Fluorimetric analysis of pesticides: Methods, recent developments and applications, Talanta, 49, 107–117 (1999).
M. C. Mahedero, A. Muñoz de la Peña, A. Bautista, J. J. Aaron, An investigation of inclusion complexes of cyclodextrins with phenylurea herbicides by photochemically- induced fluorescence. Analytical applications, J. Incl. Phenom. Macro., 42, 61–70 (2002).
A. Coly, J. J. Aaron, Simultaneous determination of binary mixtures of sulfonylurea herbicides in water by first-derivative photochemically induced spectrofluorimetry, J. AOAC Int., 84, 1745–1750 (2001).
A. Coly, J. J. Aaron, Simultaneous determination of sulfonylurea herbicide synthetic binary mixtures by a partial least square method combined with micellarenhanced photochemically-induced fluorescence for application to tap water analysis, Maced. J. Chem. Chem. Engin. ., 27, 33–40 (2009).
E. M. Almanza Lopez, A. M. Garcia-Campana, J. J. Aaron, L. Cuadra Rodriguez, Simultaneous quantification of chlorophenoxyacid herbicides based on timeresolved photochemical derivatization to induce fluorescence in micellar media, Talanta, 60, 355–367 (2003).
M. Mbaye, M. D. Gaye Seye, A. Coly, A. Tine, J. J. Aaron, Usefulness of cyclodextrin media for the determination of α-cypermethrin by photochemicallyinduced fluorescence. Analytical applications to natural waters, Anal. Bioanal. Chem., 394, 1089–1098 (2009).
F. García Sánchez, M. Cedazo, J. Lovillo, A. Navas Diaz, Variable-angle synchronous fluorescence spectrometry and rank annihilation methods for mixture resolution, Talanta, 43, 1327–1333 (1996).
G. J. Hyfantis Jr., M. S. Teglas, T. P. Finnegan, P. J. Mulligan, W. Watts, Synchronous scanning luminescence. Method to detect pesticides and explosives, Proceed. SPIE-Intern. Soc. Opt. Engin., 3853, 110– 115 (1999).
D. Picon Zamora, M. Martinez Galera, F. A. Garrido Frenich, J. L. Martinez Vidal, Trace determination of carbendazim, fuberidazole and thiabendazole in water by application of multivariate calibration to crosssections of three-dimensional excitation-emission matrix fluorescence, Analyst, 125, 1167–1174 (2000).
A. Segura, C. Cruces, A. Fernández, Determination of the pesticide carbaryl by microemulsion room-temperature phosphorescence in real samples, Anal. Sci., 12, 653–657 (1996).
Y. S. Wei, W. I. Jin, R. H. Zhu, C. S. Liu, S. S. Zhang, Determination of the pesticide carbaryl by chemical deoxygenation micellar-stabilized room temperature phosphorescence, Talanta, 41, 1617–1621 (1994).
A. Segura-Carretero, C. Cruces-Blanco, J. F. Fernandez- Sanchez, B. Canabate-Diaz, A. Fernandez- Gutiérrez, HAI-RTP determination of carbaryl pesticide in different irrigation water samples of South Spain, J. Agric. Food Chem., 48, 4453–4459 (2000).
R. G Machicote,. L. Bruzzone, . Simultaneous determination of carbaryl and 1-naphthol by first-derivative synchronous non-protected room temperature phosphorescence, Anal. Sci., 52, 623–626 (2009).
A. Alvarez-Diaz. , J. M. Costa, R. Pereiro, A. . Sanz- Medel, . Halogenated molecularly imprinted polymers for selective determination of carbaryl by phosphorescence measurements Anal. Bioanal. Chem., 394, 1569– 1576 (2009).
J. A. Murillo Pulgarín, L. F. García Bermejo, Determination of the pesticide napropamide in soil, pepper, and tomato by micelle-stabilized room-temperature phosphorescence, J. Agric. Food Chem., 50, 1002–1008 (2002).
A. Salinas-Castillo, J. F. Fernandez-Sanchez, A. Segura- Carretero, A. Fernandez-Gutiérrez, Simple determination of herbicide napropamide in water and soil samples by room-temperature phosphorescence, Pest Manag. Sci., 61, 816–820 (2005).
B. C. Diaz, A. S. Carretero, C. C. Blanco, A. F. Gutierrez, Simultaneous determination of the pesticides carbaryl and thiabendazole in environmental samples by a three-dimensional derivative variable-angle and a synchronous room-temperature phosphorescence spectroscopy, Appl. Spectrosc., 57, 1585–1591 (2003).
M. A. González-Martínez, J. Penalva, J. C. Rodríguez- Urbis, E. Brunet, A. Maquieira, R. Puchades, Immunosensors for pollutants working in organic media. Study of performances of different tracers with luminescent detection, Anal. Bioanal. Chem., 384, 1540– 1547 (2006).
I. M Ciumasu, P. M Krämer, C. M Weber, G Kolb, D. Tiemann, S. Windisch, I. Frese, A. A. Kettrup, A new, versatile field immunosensor for environmental pollutants: Development and proof of principle with TNT, diuron, and atrazine, Biosens. Bioelectron., 21, 354– 364 (2005).
M. Yu. Rubtsova, J. V. Samsonova, A. M. Egorov, R. D. Schmid, Simultaneous determination of several pesticides with chemiluminescent immunoassay on a multi-spot membrane strip, Food Agric. Immunol., 10, 223–235 (1998).
M. F. Katmeh, G. W. Aherne,, D. Stevenson, Development and evaluation of a chemiluminescent immunoassay for chlortoluron using a camera luminometer, Analyst, 121, 329–332 (1996).
G. Orellana, D. García-Fresnadillo, M. C. Moreno- Bondi, Carbamate pesticides sensing with a catalytic biosensor and molecularly engineered luminescent dyes, Afinidad, 64, 257–264 (2007).
V. S. Nunes-Halldorson, N. L. Duran, Bioluminescent bacteria: lux genes as environmental biosensors, Brazilian J. Microbiol., 34, 91–96 (2003).
S. Girotti, E. N. Ferri, M. G. Fumo, E. Maiolini, Monitoring of environmental pollutants by bioluminescent bacteria, Anal. Chim. Acta, 608, 2–29 (2008).
A. G. Hay, J. F. Rice, B. M. Applegate, N. G. Bright, G. S. Sayler, A bioluminescent whole-cell reporter for detection of 4-dichlorophenoxyacetic acid and 2,4- dichlorophenol in soil, Appl. Environ. Microbiol., 66, 4589–4594 (2000).
C. Y. Shao, C. J. Howe, A. J. R. Porter, L. A. Glover, Novel Cyanobacterial Biosensor for detection of herbicides, Appl. Environ. Microbiol., 68, 5026–5033 (2002).
S. Trajkovska, K. Tosheka, J. J. Aaron, F. Spirovski, Z. Zdravkovski Bioluminescence determination of enzyme activity of firefly luciferase in the presence of pesticides, Luminescence, 20, 192–196 (2005).
E. Vetrova, E. Esimbekova, N. Remmel, S. Kotova, N. Beloskov, V. Kratasyuk, I. Gitelson, A bioluminescent signal system: Detection of chemical toxicants in water, Luminescence, 22, 206–214 (2007).
S. Trajkovska, M. Mbaye, M. D. Gaye Seye, J. J. Aaron, M. Chevreuil, H. Blanchoud, Toxicological study of pesticides in the air and precipitations of Paris by means of a bioluminescence method, Anal. Bioanal. Chem., 394, 1099–1106 (2009).
J. L. Ren, J. Zhang, J. Q. Luo, X. K. Pei, Z. X. Jiang, Improved fluorimetric determination of dissolved aluminium by micelle-enhanced lumogallion complex in natural waters, Analyst, 126, 698–702 (2001).
Q. Wie, J. Yang, Y. Zhang, G. Chemg, B. Du, Determination of antimony(III) in environmental water samples in microemulsion system by the fluorescence quenching method, Talanta, 58, 419–426 (2002).
J. J. Aaron, M. Ely, A. Yassar, F. Rodriguez, M. Dieng, J. C. Brochon, E. Guiot, Novel fluorescent oligothiophene- 8-hydroxyquinolines for determination of heavy metal ions, Luminescence, 21, 326–328 (2006).
Y. M. Liu, M. R. Fernández de la Campa, M. E. Díaz García, A. Sanz-Medel, Micelle-stabilized liquid roomtemperature phosphorimetry for metals: The micellar reaction of gallium with 7-iodo-hydroxyquinoline-5- sulfonic acid and its application to the metal determination, Mikrochim. Acta, 103, 53–64 (1991).
B. San Vicente, J. M. Costa-Fernández, W. L. Jin, R. Pereiro, A. Sanz-Medel, Determination of trace levels of mercury in water samples based on room temperature phosphorescence energy transfer, Anal. Chim. Acta, 455, 179–186 (2002).
B. San Vincente De La Riva, J. M. Costa Fernandez, R. Pereiro, A. Sanz-Medel, Flow through luminescence for heavy metals analysis in sea water, Proceed. SPIE – Intern. Soc. Opt. Engin., 3853, 275–287 (1999).
S. M. Tauriainen, M. P. J. Virta, M. T. Karp, M. T., Detecting bioavailable toxic metals and metalloids from natural water samples using luminescent sensor bacteria, Water Research, 34, 2661–2666 (2000).
Y.-J. Fu, W.-L. Chen, Q.-Y. Huang, Construction of two lux-tagged Hg2+-specific biosensors and their luminescence performance, Appl. Microbiol. Biotechnol., 79, 363–370 (2008).
T. Okuda, D. Naoi, M. Tenmoku, S. Tanaka, K. He, Y. Ma, F. Yang, Y. Lei, Y. Jia, D. Zhang, Polycyclic aromatic hydrocarbons (PAHs) in the aerosol in Beijing, China, measured by aminopropylsilane chemicallybonded stationary-phase column chromatography and HPLC/fluorescence detection, Chemosphere, 65, 427– 435 (2006).
Y. Alnouti, K. Srinivasan, D. Waddell, H. Bi, O. Kavetskaia, A. Gusev, Development and application of a new on-line SPE system combined with LC–MS/MS detection for high throughput direct analysis of pharmaceutical compounds in plasma, J. Chrom. A, 1080, 99–106 (2005).
L. Oliferova, M. Statkus, G. Tsysin, O. Shpigun, Y. Zolotov, On-line solid-phase extraction and HPLC determination of polycyclic aromatic hydrocarbons in water using fluorocarbon polymer sorbents, Anal. Chim. Acta, 538, 35–40 (2005).
J. Li, L. Chen, X. Wang, H. Jin, L. Ding, K. Zhang, H. Zhang, Determination of tetracyclines residues in honey by on-line solid-phase extraction high-performance liquid chromatography, Talanta, 75, 1245–1252 (2008).
K. Mitani, S. Narimatsu, H. Kataoka, Determination of daidzein and genistein in soybean foods by automated on-line in-tube solid-phase microextraction coupled to high-performance liquid chromatography, J. Chrom. A, 986, 169–177 (2003).
S. Wang, W. Huang, G. Fang, J. He, Y. Zhang, On-line coupling of solid-phase extraction to high-performance liquid chromatography for determination of estrogens in environment, Anal. Chim. Acta, 606, 194–201 (2008).
T. Okuda, K. Okamoto, S. Tanaka, Z. Shen, Y. Han, Z. Huo, Measurement and source identification of polycyclic aromatic hydrocarbons (PAHs) in the aerosol in Xi'an, China, by using automated column chromatography and applying positive matrix factorization (PMF), Sci. Total Environ., 408, 1909–1914 (2010).
T. Hien, P. Nam, S. Yasuhiro, K. Takayuki, T. Norimichi, B. Hiroshi, Comparison of particle-phase polycyclic aromatic hydrocarbons and their variability causes in the ambient air in Ho-Chi-Minh City, Vietnam and in Osaka, Japan, during 2005–2006, Sci. Total Environ., 382, 70–81 (2007).
A. Bacaloni, C. Cafaro, L. De Giorgi, R. Ruocco, L. Zoccolillo, Improved analysis of polycyclic aromatic hydrocarbons in atmospheric particulate matter by HPLC fluorescence, Ann. Chim., 94, 751–759 (2004).
O. Delhomme, P. Herckes, M. Millet, Determination of nitro-polycyclic aromatic hydrocarbons in atmospheric aerosols using HPLC fluorescence with a post-column derivatisation technique, Anal. Bioanal. Chem., 389, 1953–1959 (2007).
M. Rynö, L. Rantanen, E. Papaioannou, A. G. Konstandopoulos, T. Koskentalod, K. Savela, Comparison of pressurized fluid extraction, Soxhlet extraction and sonication for the determination of polycyclic aromatic hydrocarbons in urban air and diesel exhaust particulate matter, J. Environ. Monit., 8, 488–493 (2006).
C. Schauer, R. Niessner, U. Pöschl, Analysis of nitrated polycyclic aromatic hydrocarbons by liquid chromatography with fluorescence and mass spectrometry detection: air particulate matter, soot, and reaction product studies, Anal. Bioanal. Chem., 378, 725–736 (2004).
A. Šišović, I. Bešlić, K. Šega, V. Vadjić, PAH mass concentrations measured in PM10 particle fraction, Environ. International. 34, 580–584 (2008).
O. Delhomme, E. Rieb, M. Millet, Polycyclic aromatic hydrocarbons analyzed in rainwater collected on two sites in east of France (Strasbourg and Erstein), Polycyclic Aromat. Compd., 28, 472–485 (2008).
M. Bourdat-Deschamps, J. J. Daudin, E. Barriuso, An experimental design approach to optimise the determination of polycyclic aromatic hydrocarbons from rainfall water using stir bar sorptive extraction and high performance liquid chromatography-fluorescence detection, J. Chromatogr. A, 1167 143–153 (2007).
L. Tolun, D. Martens, O. S. Okay, K. W. Schramm, Polycyclic aromatic hydrocarbon contamination in coastal sediments of the Izmit Bay (Marmara Sea): Case studies before and after the Izmit Earthquake, Environ. International, 32, 758–765 (2006).
C. Vane, I. Harrison, A. Kim, Polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in sediments from the Mersey Estuary, U. K., Sci. Total Environ., 374, 112–126 (2007).
N. Bihari, M. Fafandel, B. Hamer, B. Kralj-Bilen, PAH content, toxicity and genotoxicity of coastal marine sediments from the Rovinj area, Northern Adriatic, Croatia, Sci. Total Environ., 366, 602–611 (2006).
D. Sanger, A. Holland, G. Scott, Tidal creek and salt marsh sediments in South Carolina Coastal Estuaries: II. Distribution of organic contaminants, Arch. Environ. Contam. Toxicol., 37, 458–471 (1999).
Y. Song, B. Wilke, X. Song, P. Gong, Q. Zhou, G. Yang, Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and heavy metals (HMs) as well as their genotoxicity in soil after long-term wastewater irrigation, Chemosphere, 65 1859–1868 (2006).
R. Barra, P. Popp, R. Quiroz, C. Bauer, H. Cid, W. von Tümpling, Persistent toxic substances in soils and waters along an altitudinal gradient in the Laja River Basin, Central Southern Chile, Chemosphere, 58, 905– 915 (2005).
L. Chrysikou, P. Gemenetzis, A. Kouras, E. Manoli, E. Terzi, C. Samara, Distribution of persistent organic pollutants, polycyclic aromatic hydrocarbons and trace elements in soil and vegetation following a large scale landfill fire in northern Greece, Environ. Intern., 34, 210–225 (2008).
J. Gasperi. S. Garnaud, V. Rocher, R. Moilleron, Priority pollutants in surface waters and settleable particles within a densely urbanised area: case study of Paris (France), Sci. Total Environ., 407, 2900–2908 (2009).
M. Pena, M. Casais, M. Mejuto, R. Cela, Development of an ionic liquid based dispersive liquid–liquid microextraction method for the analysis of polycyclic aromatic hydrocarbons in water samples, J. Chromatogr. A, 1216, 6356–6364 (2009).
E. Escartín, C. Porte, Biomonitoring of PAH pollution in high-altitude mountain lakes through the analysis of fish bile, Environ. Sci. Technol., 33, 406–409 (1999).
H. Schulz, P. Popp, G. Huhn, H. Stärk, G. Schürmann, Biomonitoring of airborne inorganic and organic pollutants by means of pine tree barks. I. Temporal and spatial variations, Sci. Total Environ., 232, 49–58 (1999).
C. Alonso-Alvarez, I. Munilla, M. López-Alonso, A. Velando, Sublethal toxicity of the Prestige oil spill on yellow-legged gulls, Environ. Intern., 33, 773–781 (2007).
L. Fua, X. Liub, J. Hub, X. Zhaob, H. Wangc, X. Wanga, Application of dispersive liquid–liquid microextraction for the analysis of triazophos and carbaryl pesticides in water and fruit juice samples, Anal. Chim. Acta, 632, 289–295 (2009).
R. C. Prados-Rosales, M. C. Herrera, J. L. Luque- García, M. D. Luque de Castro, Study of the feasibility of focused microwave-assisted Soxhlet extraction of Nmethylcarbamates from soil, J. Chromatogr. A, 953, 133–140 (2002).
H. Li, J. Li, G. Li, J. Jen, Simultaneous determination of airborne carbamates in workplace by high performance liquid chromatography with fluorescence detection, Talanta, 63, 547–553 (2004).
T. Pérez-Ruiz, C. Martínez-Lozano, V. Tomás, J. Martín, High-performance liquid chromatographic assay of phosphate and organophosphorus pesticides using a post-column photochemical reaction and fluorimetric detection, Anal. Chim. Acta, 540, 383–391 (2005).
B. Le Bot, K. Colliaux, D. Pelle, C. Briens, R. Seux, M. Clément, Optimization and performance evaluation of the analysis of glyphosate and AMPA in water by HPLC with fluorescence detection, Chromatographia, 56, 161–164 (2005).
A. López, D. Vega, M. E. Torres, Z. Sosa, J. J. Santana, Solid-phase microextraction of benzimidazole fungicides in environmental liquid samples and HPLC– fluorescence determination, Anal. Bioanal. Chem., 387, 1957–1963 (2007).
H. Z. Lian, Y. F. Kang, A. Yasin, S. P. Bi, D. L. Shao, Y. J. Chen, L. M. Dai, L. C. Tia, Determination of aluminium in environmental and biological samples by reversed- phase high-performance liquid chromatography via pre-column complexation with morin, J. Chromatogr. A, 993, 179–185 (2003).
T. Umemuraa, Y. Usamia, S. Aizawaa, K. Tsunodaa, K. Satakeb, Seasonal change in the level and the chemical forms of aluminium in soil solution under a Japanese cedar forest, Sci. Total Environ., 317, 149–157 (2003).
J. L. Santos, I. Aparicio, E. Alonso, M. Callejón, Simultaneous determination of pharmaceutically active compounds in wastewater samples by solid phase extraction and high-performance liquid chromatography with diode array and fluorescence detectors, Anal. Chim. Acta, 550, 116–122 (2005).
M. Sturini, A. Speltini, L. Pretali, E. Fasani, A. Profumo, Solid-phase extraction and HPLC determination of fluoroquinolones in surface waters, J. Sep. Sci., 32, 3020–3028 (2009).
M. Granados, M. Encabo, R. Compañó, M. D. Prat, Determination of Tetracyclines in Water Samples Using Liquid Chromatography with Fluorimetric Detection, Chromatographia, 61, 471–477 (2005).
J. L. Santos, I. Aparicio, E. Alonso, Occurrence and risk assessment of pharmaceutically active compounds in wastewater treatment plants. A case study: Seville city (Spain), Environ. Intern., 33, 596–601 (2007).
X. Peng, Z. Wang, W. Kuang, J. Tan, K. Li, A preliminary study on the occurrence and behavior of sulfonamides, ofloxacin and chloramphenicol antimicrobials in wastewaters of two sewage treatment plants in Guangzhou, China, Sci. Total Environ., 371, 314–322 (2006).
E. M. Golet, A. C. Alder, A. Hartmann, T. A. Ternes, W. Giger, Trace determination of fluoroquinolone antibacterial agents in urban wastewater by solid-phase extraction and liquid chromatography with fluorescence detection, Anal. Chem., 73, 3632–3638 (2001).
X. Peng, J. Tan, C. Tang, Y. Yu, Z. Wang, Multiresidue determination of fluoroquinolone, sulfonamide, trimethoprim, and chloramphenicol antibiotics in urban waters in China, Environ. Toxicol. Chem., 27, 73–79 (2008).
M. Seifrtová, A. Pena, C. M. Lino, P. Solich, Determination of fluoroquinolone antibiotics in hospital and municipal wastewaters in Coimbra by high performance liquid chromatography using a monolithic column and fluorescence detection, Anal. Bioanal. Chem., 391, 799–805 (2008).
A. V. Herrera-Herrera, J. Hernandez-Borges, M. A. Rodríguez-Delgado, Ionic liquids as mobile phase additives for the high-performance liquid chromatographic analysis of fluoroquinolone antibiotics in water samples, Anal. Bioanal. Chem, 392, 1439–1446 (2008).
A. Pena, D. Chmielova, C. M. Lino, P. Solich, Determination of fluoroquinolone antibiotics in surface waters from Mondego River by high performance liquid chromatography using a monolithic column, J. Sep. Sci., 30, 2924–2928 (2007).
L. Zhao, Y. H. Dong, H. Wang, Residues of veterinary antibiotics in manures from feedlot livestock in eight provinces of China, Sci. Total Environ., 408, 1069– 1075 (2010).
B. J. Robinson, J. Hellou, Biodegradation of endocrine disrupting compounds in harbour seawater and sediments, Sci. Total Environ., 407, 5713–5718 (2009).
P. A. Blackwell, H. C. Holten, H. P Mab, B. Halling- Sørensen, A. B. A. Boxall, P. Kaya, Ultrasonic extraction of veterinary antibiotics from soils and pig slurry with SPE clean-up and LC–UV and fluorescence detection, Talanta 64, 1058–1064 (2004).
M. Ö. Uslu, A. Yediler, I. A. Balcıoğlu, S. Schulte- Hostede, Analysis and Sorption Behavior of Fluoroquinolones in Solid Matrices, Water Air Soil Pollut, 190, 55–63 (2008).
M. D. Prat, D. Ramil, R. Compañó, J. A. Hernández- Arteseros, M. Granados, Determination of flumequine and oxolinic acid in sediments and soils by microwaveassisted extraction and liquid chromatography-fluorescence, Anal. Chim. Acta, 567, 229–235 (2006).
L. K. Sørensen, H. Hansen, Determination of oxolinic acid in marine sediments by HPLC with fluorescence detection, J. Liq. Chromatogr. Relat. Technol., 24, 2469–2476 (2001).
S. Morales-Muñoz, J. L. Luque-García, M. D. Luque de Castro, Continuous microwave-assisted extraction coupled with derivatization and fluorimetric monitoring for the determination of fluoroquinolone antibacterial agents from soil samples, J. Chromatogr. A, 1059, 25–31 (2004).
J. S. Ra, S. Y Oh, B. C. Lee, S. D. Kim, The effect of suspended particles coated by humic acid on the toxicity of pharmaceuticals, estrogens, and phenolic compounds, Environ. Intern., 34, 184–192 (2008).
R. Delépée, H. Pouliquen, H. Le Bris, The bryophyte Fontinalis antipyretica Hedw. bioaccumulates oxytetracycline, flumequine and oxolinic acid in the freshwater environment, Sci. Total Environ., 322, 243– 253 (2004).
F. Tagliaro, G. Manetto, F. Crivellente, F. P. Smith, A brief introduction to capillary electrophoresis, Forensic Sci. Int., 92, 75–88 (1998).
K. D. Altria, Overview of capillary electrophoresis and capillary electrochromatography, J. Chromatogr. A, 856, 443–463 (1999).
P. Puig, F. Borrull, M. Calull, C. Aguilar, Recent advances in coupling solid-phase extraction and capillary electrophoresis (SPE–CE), Trends Anal. Chem., 26, 664–678 (2007).
B. M. Simonet, A. Ríos, M. Valcárcel, Enhancing sensitivity in capillary electrophoresis, Trends Anal. Chem., 22, 605–614 (2003).
S. L. Simpson Jr., J. P. Quirino, S. Terabe, On-line sample preconcentration in capillary electrophoresis. Fundamentals and applications, J. Chromatogr. A, 1184, 504–541 (2008).
J. S. Fritz, The role of organic solvents in the separation of nonionic compounds by capillary electrophoresis, Electrophoresis, 24, 1530–1536 (2003).
M. G. Garguilo, D. H. Thomas , D. S. Anex , D. J. Rakestraw, Laser-induced dispersed fluorescence detection of polycyclic aromatic compounds in soil extracts separated by capillary electrochromatography, J. Chromatogr. A, 883, 447–452 (2000).
D. Norton, S. A. Shamsi, Capillary electrochromatography of methylated benzo
[a]pyrene isomers. II. Effect of stationary phase tuning, J. Chromatogr. A, 1008, 217–232 (2003).
A. Cantó-Mirapeix, J. M. Herrero-Martínez, C. Mongay- Fernández, E. F. Simó-Alfonso, CEC column behaviour of butyl and lauryl methacrylate monoliths prepared in non-aqueous media, Electrophoresis, 30, 607–615 (2009).
D. A. Stead, R. G. Reid, R. B. Taylor, Capillary electrochromatography of steroids: Increased sensitivity by on-line concentration and comparison with highperformance liquid chromatography, J. Chromatogr. A, 798, 259–267 (1998).
L. Geiser, J. L. Veuthey, Non-aqueous capillary electrophoresis 2005–2008, Electrophoresis, 30, 36–49 (2009).
S. J. Kok, I. C. Isberg, C. Gooijer, U. Brinkman, N. H. Velthorst, Ultraviolet laser-induced fluorescence detection strategies in capillary electrophoresis: determination of naphthalene sulphonates in river water, Anal. Chim. Acta, 360, 109–118 (1998).
R. Loos, R. Niessner, Analysis of aromatic sulfonates in water by solid-phase extraction and capillary electrophoresis, J. Chromatogr. A, 822, 291–303 (1998).
D. Martínez, M. J. Cugat, F. Borrull, M. Calull, Solidphase extraction coupling to capillary electrophoresis with emphasis on environmental analysis, J. Chromatogr. A, 902, 65–89 (2000).
R. Ramautar, G. W. Somsen, G. J. de Jong, Recent developments in coupled SPE-CE, Electrophoresis, 27, 4694–4702 (2010).
M. Marlow, R. J. Hurtubise, Liquid–liquid–liquid microextraction for the enrichment of polycyclic aromatic hydrocarbon metabolites investigated with fluorescence spectroscopy and capillary electrophoresis, Anal. Chim. Acta, 526, 41–49 (2004).
P. M. do Rosário, J. M. Nogueira, Combining stir bar sorptive extraction and MEKC for the determination of polynuclear aromatic hydrocarbons in environmental and biological matrices, Electrophoresis, 27, 4694– 4702 (2006).
J. Hernández-Borges, S. Frías-García, A. Cifuentes, M. A. Rodríguez-Delgado, Pesticide analysis by capillary electrophoresis, J. Sep. Sci., 27, 947–963 (2004).
M. Molina, M. Silva, In-capillary derivatization and analysis of amino acids, amino phosphonic acid-herbicides and biogenic amines by capillary electrophoresis with laser-induced fluorescence detection, Electrophoresis, 23, 2333–2340 (2002).
T. Tegeler, Z. El Rassi, Capillary electrophoresis and electrochromatography of pesticides and metabolites, Electrophoresis, 22, 4281–4293 (2001).
Y. Picó, R. Rodríguez, J. Mañes, Capillary electrophoresis for the determination of pesticide residues, Trends Anal. Chem., 22, 133–151 (2003).
Y. Picó, Capillary electrophoresis, environmental applications, Encyclopedia of Analytical Science, 362– 374 (2005).
M. Asensio-Ramos, Javier Hernández-Borges, L. M. Ravelo-Pérez, M. A. Rodríguez-Delgado, Simultaneous determination of seven pesticides in waters using multiwalled carbon nanotube SPE and NACE, Electrophoresis, 29, 4412–4421 (2008).
E. Rodríguez-Gonzalo, L. Ruano-Miguel, R. Carabias- Martínez, In-capillary microextraction using monolithic polymers: Application to preconcentration of carbamate pesticides prior to their separation by MEKC, Electrophoresis, 30, 1913–1922 (2009).
R. Carabias-Martínez, E. Rodríguez-Gonzalo, J. Domínguez- Alvarez, C. García-Pinto, J. Hernández-Méndez, Prediction of the behaviour of organic pollutants using cloud point extraction, J. Chromatogr. A, 1005, 23–34 (2003).
A. Juan-García, Y. Picó, G. Font, Capillary electrophoresis for analyzing pesticides in fruits and vegetables using solid-phase extraction and stir-bar sorptive extraction, J. Chromatogr. A, 1073, 229–236 (2005).
R. Carabias-Martínez, E. Rodríguez-Gonzalo, E. Miranda- Cruz, J. Domínguez-Álvarez, J. Hernández-Méndez, Sensitive determination of herbicides in food samples by nonaqueous CE using pressurized liquid extraction, Electrophoresis, 28, 3606–3616 (2007).
M. Silva, Micellar electrokinetic chromatography: Methodological and instrumental advances focused on practical aspects, Electrophoresis, 30, 50–64 (2009).
S. Chen, Y. Xu, Y. Bi, W. Du, B. F. Liu, Analysis of environmental pollutants metabolized from pesticides using capillary electrophoresis with multiphoton-excited fluorescence detection, Talanta, 70, 63–67 (2006).
J. Jiang, C. A. Lucy, Determination of glyphosate using off-line ion exchange preconcentration and capillary electrophoresis-laser induced fluorescence detection, Talanta, 72, 113–118 (2007).
W. Wall, J. Li, Z. El Rassi, Electrically driven microseparation methods for pesticides and metabolites Part VII: Capillary electrophoresis and electrochromatography of derivatized and underivatized phenol pesticidic metabolites. Preconcentration and laser induced fluorescence detection of dilute samples, J. Sep. Sci., 25, 1231–1244 (2002).
R. Zhu, W. T. Kok, Determination of trace metal ions by capillary electrophoresis with fluorescence detection based on post-column complexation with 8-hydroxyquinoline- 5-sulphonic acid, Anal. Chim. Acta, 371, 269–277 (1998).
K. Isoo, S. Terabe, Metal complex separation with online sample preconcentration in micellar electrokinetic chromatography, Anal. Sci., 21, 43–47 (2005).
W. Liu, H. K. Lee, Simultaneous analysis of lead, mercury and selenium species by capillary electrophoresis with combined ethylenediaminetetraacetic acid complexation and field-amplified stacking injection, Electrophoresis, 20, 2475–2483 (1999).
Z. Zhu, L. Zhang, A. Marimuthu, Z. Yang, Largevolume sample stacking for analysis of ethylenediaminetetraacetic acid by capillary electrophoresis, Electrophoresis, 23, 2880–2887 (2002).
H. Okamoto, Y. Okamoto, T. Hirokawa, A. R. Timerbaev, Trace ion analysis of sea water by capillary electrophoresis: determination of strontium and lithium pre-concentrated by transient isotachophoresis, Analyst, 128, 1439–1442 (2003).
A. Takatsu, S. Eyama, A. Uchiumi, Determination of Aluminum in Serum by Capillary Zone Electrophoresis with Laser-lnduced Fluorescence Detection, Chromatographia, 40, 125–128 (1995).
S. Y. Chang, H. T. Chiang, Simultaneous determination of selenium and antimony compounds by capillary electrophoresis with indirect fluorescence detection, Electrophoresis, 23, 2913–2917 (2002).
S. Saito, R. Suzuki, N. Danzaka, A. Hikichi, K. Yoshimoto, M. Maeda, M. Aoyama, Direct fluorometric detection of paramagnetic and heavy metal ions at subamol level using an aromatic polyaminocarboxylate by CZE: Combination of pre- and on-capillary complexation technique, Electrophoresis, 28, 2448–2457 (2007).
S. Saito, J. Shimidzu, K. Yoshimoto, M. Maeda, M. Aoyama, Selective ultratrace detection of Al(III) and Ga(III) complexed with a calcein isomer by capillary zone electrophoresis with laser-induced fluorescence detection: Comparison of emissive polyaminocarboxylates as derivatizing ligands, J. Chromatogr. A, 1140, 230–235 (2007).
L. Ma, J. Kang, Determination of mercury ion by MEKC with on-column derivatisation and LIF detection, J. Sep. Sci., 31, 888–892 (2008).
J. M. Lemus-Gallego, J. Perez-Arroyo, Determination of hydrocortisone, polymyxin B and Zn-bacitracin in pharmaceutical preparations by micellar electrokinetic chromatography, Anal. Bioanal. Chem., 375, 617–622 (2003)
A. Macià , F. Borrull, M. Calull, C. Aguilar, Analysis of nonsteroidal anti-inflammatory drugs in water samples using microemulsion electrokinetic capillary chromatography under pH-suppressed electroosmotic flow with an on-column preconcentration technique, Chromatographia, 63, 149–154 (2006).
J. M. Serrano, M. Silva, Trace analysis of aminoglycoside antibiotics in bovine milk by MEKC with LIF detection, Electrophoresis, 27, 4703–4710 (2006).
T. D. Laing, A. J. Marenco, D. M. Moore, G. J. Moore, D. C. Mah, W. E. Lee, Capillary electrophoresis laserinduced fluorescence for screening combinatorial peptide libraries in assays of botulinum neurotoxin A, J. Chromatogr. B, 843, 240–246 (2006).
W. Wang, C. Li, Y. Li, Z. Hu, X. Chen, Rapid and ultrasensitive determination of ephedrine and pseudoephedrine derivatizated with 5-(4,6-dichloro-s-triazin- 2-ylamino) fluorescein by micellar electrokinetic chromatography with laser-induced fluorescence detection, J. Chromatogr. A, 1102, 273–279 (2006).
J. C. Hudson, M. Golin, M. Malcolm, C. F. Whiting, Capillary zone electrophoresis in a comprehensive screen for drugs of forensic interest in whole blood: an update, Can. Soc. Forensic. Sci. J., 31, 1–29 (1998).
A. Musengaa, E. Kenndler, E. Morgantia, F. Rasic, M. A. Raggi, Analysis of the anti-Parkinson drug pramipexole in human urine by capillary electrophoresis with laser-induced fluorescence detection, Anal. Chim. Acta, 626, 89–96 (2008).
A. Musenga, M. Amore, R. Mandrioli, E. Kenndlerc, L. de Martino, M. Augusta Raggi, Determination of duloxetine in human plasma by capillary electrophoresis with laser-induced fluorescence detection, J. Chromatogr. B, 877, 1126–1132 (2009).
M. Hernández, F. Borrull, M. Calull, Analysis of antibiotics in biological samples by capillary electrophoresis, Trends Anal. Chem., 22, 416–427 (2003).
J. Ruzicka, E. H. Hansen, Retro-review of flowinjection analysis, Trends Anal. Chem., 27, 390–393 (2008).
M. A. Segundo, L. M. Magalhaes, Multisyringe flow injection analysis: State-of-the-art and perspectives, Anal. Sci., 22, 3–8 (2006).
J. Ruzicka, E. H. Hansen, Flow injection analyses. Part I. A new concept of fast continuous flow analysis, Anal. Chim. Acta , 78, 145–157 (1975).
X. Wang, M. L. Liu, X. L. Cheng, J. M. Lin, Flowbased luminescence-sensing methods for environmental water analysis, Trends Anal. Chem., 28, 75–87 (2009).
J. F. Fernández-Sánchez, A. S. Carretero, C. Cruces- Blanco, A. Fernández-Gutiérrez, Highly sensitive and selective fluorescence optosensor to detect and quantify benzo
[a]pyrene in water samples, Anal. Chim. Acta , 506, 1–7 (2004).
J. F. Fernández-Sánchez, A. Segura-Carretero, J. M. Costa-Fernández, N. Bordel, R. Pereiro, C. Cruces- Blanco, A. Sanz-Medel, A. Fernández-Gutiérrez, Fluorescence optosensors based on different transducers for the determinativos of polycyclic aromatic hydrocarbons in water, Anal. Bioanal. Chem., 377, 614– (2003).
J. F. Fernández-Sánchez, A. S. Carretero, C. Cruces- Blanco, A. Fernández-Gutiérrez, The development of solid-surface fluorescence characterization of polycyclic aromatic hydrocarbons for potential screening tests in environmental samples, Talanta, 60, 287–293 (2003).
J. A. Erustes, A. Andrade-Eiroa, A. Cladera, R. Forteza, V. Cerdà, Fast sequential injection determination of benzo
[a]pyrene using variable angle fluorescence with on-line solid-phase extraction, Analyst, 126, 451– 456 (2001).
A. Domínguez-Vidal, P. Ortega-Barrales, A. Molina- Díaz, Environmental water samples analysis of pesticides by means of chemometrics combined with fluorimetric multioptosensing, J. Fluoresc., 17, 271– 277 (2007).
G. S. Furzer, L. Veldhuis, J. C. Hall, Development and comparison of three diagnostic immunoassay formats for the detection of azoxystrobin, J. Agric. Food Chem., 54, 688–693 (2006).
I. Súbová, A. K. Assandas, M. C. Icardo, J. M. Calatayud, Fluorescence determination of the pesticide asulam by flow injection analysis, Anal. Sci., 22, 21–24 (2006).
S. Irace-Guigand, E. Leverend, M. D. Gaye-Seye, J. J. Aaron, A new on-line micellar-enhanced photochemically- induced fluorescence method for determination of phenylurea herbicide residues in water, Luminescence, 20, 138–142 (2005).
M. Šandor, F. Geistmann, M. Schuster, Luminescent hexanuclear Cu(I)-cluster for the selective determination of copper, Anal. Chim. Acta, 486, 11–19 (2003).
J. Ueberfeld, N. Parthasarathy, H. Zbinden, N. Gisin, J. Buffle, Coupling fiber optics to a permeation liquid membrane for heavy metal sensor development, Anal. Chem., 74, 664–670 (2002).
C. Cano-Raya, M. D. Fernández-Ramos, L. F. Capitán- Vallvey, Fluorescence resonance energy transfer disposable sensor for copper(II), Anal. Chim. Acta, 555, 2 (2006) 299.
S. Meseguer-Lloret, P. Campin-Falco, S. Cárdenas, M. Gallego, M. Valcarcel, FI automatic method for the determination of copper(II) based on coproporphyrin ICu( II)/TCPO/H2O2 chemiluminescence reaction for the screening of waters, Talanta, 64, 1030–1035 (2004).
H. Wu, Y. Jin, W. Han, Q. Miao, S. Bi, Nonchromatographic speciation analysis of mercury by flow injection on-line preconcentration in combination with chemical vapor generation atomic fluorescence spectrometry, Spectrochim. Acta. Part. B At. Spec., 61, 831–840 (2006).
A. M. Serra, J. M. Estela, V. Cerdà, MSFIA system for mercury determination by cold vapour technique with atomic fluorescence detection, Talanta, 77, 556–560 (2008).
Y. Xu, F. G. Bessoth, J. C. T. Eijkel, A. Manz, On-line monitoring of chromium(III) using a fast micromachined mixer/reactor and chemiluminescence detection, Analyst, 125, 677–683 (2000).
C. Xiao, D. W. King, D. A. Palmer, D. J. Wesolowski, Study of enhancement effects in the chemiluminescence method for Cr(III) in the ng l−1 range, Anal. Chim. Acta, 415, 209–219 (2000).
W. Som-Aum, J. Threeprom, H. F. Li, J. M. Lin, Determination of chromium(III) and total chromium using dual channels on glass chip with chemiluminescence detection, Talanta, 71, 2062–2068 (2007).
A. Economou, A. K. Clark, P. R. Fielden, Determination of Co(II) by chemiluminescence after in situ electrochemical pre-separation on a flow-through mercury film electrode, Analyst, 126, 109–113 (2001).
L. A. Tortajada-Genaro, P. Campins-Falco, F. Bosch- Reig, Analyser of chromium and/or cobalt, Anal. Chim. Acta, 488, 243–254 (2003).
M. Li, S. H. Lee, Determination of As(III) and As(V) ions by chemiluminescence method, Microchem. J., 80, 237–240 (2005).
L. N. Li, N. B. Li, H. Q. Luo, A new chemiluminescence method for the determination of nickel ion, Spectrochim. Acta, Part A, 64, 391–396 (2006).
V. Cannizzaro, A. R. Bowie, A. Sax, E. P. Achterberg, P. J. Worsfold, Determination of cobalt and iron in estuarine and coastal waters using flow injection with chemiluminescence detection, Analyst, 125, 51–57 (2000).
E. K. Paleologos, C. D. Stalikas, S. M. Tzouwara- Karayanni, M. I. Karayannis, Selective speciation of trace chromium through micelle-mediated preconcentration, coupled with micellar flow injection analysis– spectrofluorimetry, Anal. Chim. Acta, 436, 49–57 (2001).
E. K. Paleologos, A. G. Vlessidis, M. I. Karayannis, N. P. Evmiridis, On-line sorption preconcentration of metals based on mixed micelle cloud point extraction prior to their determination with micellar chemiluminescence: Application to the determination of chromium at ng l−1 levels, Anal. Chim. Acta, 477, 223–231 (2003).
E. K Paleogos, M. A. Koupparis, M. I. Karayannis, P. G. Veltsistas, Nonaqueous catalytic fluorimetric trace analysis of vanadium bases on the pyronine Bhydrogen peroxide reaction and flow injection after cloud point extraction, Anal. Chem., 74, 664–670 (2002).
M. I. Acedo-Valenzuela, T. Galeano-Díaz, N. Mora- Díez, A. Silva-Rodríguez, Response surface methodology for the optimisation of flow-injection analysis with in situ solvent extraction and fluorimetric assay of tricyclic antidepressants, Talanta, 66, 952–960 (2005).
A. G. Lista, M. E. Palomeque, B. S. Fernández-Band, A fast fluorimetric flow injection method to determine ibuprofen, J. Braz. Chem. Soc., 17, 1428–1431 (2006).
D. A. Lerner, M. A. Martin, Luminescence in organized media and supramolecular interactions: physicochemical aspects and applications, Analusis, 28, 649– 663 (2000).
J. J. Juan Santana-Rodríguez, Z. Sosa-Ferrera, D. Vega-Moreno, M. E. Torres-Padrón, C. Mahugo- Santana, Recent trends in the use of organized molecular systems combined with chromatographic techniques in environmental analysis, Anal. Bioanal. Chem., 391, 725–733 (2008).
S. Montesdeoca-Esponda, M. E. Torres-Padrón, Z. Sosa- Ferrera, J. J. Juan Santana-Rodríguez, Solid-phase microextraction with micellar desorption and HPLC-fluorescence detection for the analysis of Fluoroquinolones residues in water samples, Anal. Bioanal. Chem., 394, 927–935 (2009).
Y. Wu, L. Xia, R. Chen, B. Hu, Headspace single drop microextraction combined with HPLC for the determination of trace polycyclic aromatic hydrocarbons in environmental samples, Talanta, 74, 470–477 (2008).
E. K. Paleologos, D. L. Giokas, M. I. Karayannis, Micelle- mediated separation and cloud-point extraction, Trends Anal. Chem., 24, 426–436 (2005).
A. Eiguren-Fernández, Z. Sosa-Ferrera, J. J. Santana- Rodríguez, Application of cloud-point methodology to the determination of polychlorinated dibenzofurans in sea water by high-performance liquid chromatography, Analyst, 124, 487–491 (1999).
A. Eiguren-Fernández, Z. Sosa-Ferrera, J. J. Santana- Rodríguez, Determination of polychlorinated biphenyls by liquid chromatography following cloud-point extraction, Anal. Chim. Acta., 358, 145–155 (1998).
D. Sicilia, S. Rubio, D. Pérez-Bendito, N. Maniasso, E. A. G. Zagatto, Anionic surfactants in acid media: a new cloud point extraction approach for the determination of polycyclic aromatic hydrocarbons in environmental samples, Anal. Chim. Acta., 392, 29–38 (1999).
E. K. Paleologos, M. A. Koupparis, M. I. Karayannis, P. G. Veltsistas, Nonaqueous catalytic fluorometric trace determination of vanadium based on the pyronine B-hydrogen peroxide reaction and flow injection after cloud point extraction , Anal. Chem., 73, 4428–4433 (2001).
A. Eiguren-Fernández, Z. Sosa-Ferrera, J. J. Santana- Rodríguez, Microwave-assisted extraction of organochlorine compounds in marine sediments with organized molecular systems, Chromatographia, 53, 375–379 (2001).
F. Merino, S. Rubio, D. Pérez-Bendito, Acid-induced cloud point extraction and preconcentration of polycyclic aromatic hydrocarbons from environmental solid samples, J. Chromatogr. A, 962, 1–8 (2002).
A. Eiguren-Fernández, Z. Sosa-Ferrera, J. J. Santana- Rodríguez, Application of microwave-assisted extraction using micellar media to the determination of polychlorinated biphenyls in marine sediments, Anal. Chim. Acta., 433, 237–244 (2001).
A. Moral, D. Sicilia, S. Rubio, D. Pérez-Bendito, Sodium dodecyl sulphate-coated alumina for the extraction/ preconcentration of benzimidazolic fungicides from natural waters prior to their quantification by liquid chromatography/fluorimetry, Anal. Chim. Acta., 369, 132–138 (2006).
M. Marlow, R. J. Hurtubise, Separation and detection of a benzo
[a]pyrene metabolite with capillary electrophoresis in the presence of DNA using laser-induced fluorescence, Talanta, 57, 193–201 (2002).
C. J. Smith, J. Grainer, D. G. Patterson Jr, Separation of polycyclic aromatic hydrocarbon metabolites by γ- cyclodextrin-modified micellar electrokinetic chromatography with laser-induced fluorescence detection, J. Chromatogr. A, 803, 241–247 (1998).
J. Kuijt, C. García-Ruiz, G. J. Stroomberg, M. L. Marina, F. Ariese, U. A. Th. Brinkman, C. Gooijer, Laserinduced fluorescence detection at 266 nm in capillary electrophoresis Polycyclic aromatic hydrocarbon metabolites in biota, J. Chromatogr. A, 907, 291–299 (2001).
J. H. T. Luong, The combined effect of acetonitrile and urea on the separation of polycyclic aromatic hydrocarbons using sodium dioctyl sulfosuccinate in electrokinetic chromatography, Electrophoresis, 19, 1461–1467 (1998).
W. Wall, Z. El Rassi, Electrically driven microseparation methods for pesticides and metabolites: V. Micellar electrokinetic capillary chromatography of aniline pesticidic metabolites derivatized with fluorescein isothiocyanate and their detection in real water at low levels by laser-induced fluorescence, Electrophoresis, 22, 2312–2319 (2001).
M. Navarrete-Casas, A. Segura-Carretero, C. Cruces- Blanco, A. Fernández-Gutiérrez, Potential determination of aminated Pesticides and metabolites by cyclodextrin capillary electrophoresis–laser-induced fluorescence using FITC as labeling, Pest. Manag. Sci., 61,197–203 (2005).
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