Simultaneous determination of sulfonylurea herbicide synthetic binary mixtures by a partial least square method combined with micellar-enhanced photochemically-induced fluorescence application to tap water analysis
DOI:
https://doi.org/10.20450/mjcce.2009.219Keywords:
partial least square, micellar-enhanced photochemically-induced fluorescence, sulfonylurea herbicides, tap water analysisAbstract
A combination of the partial least square method in its first variable (PLS-1) with micellar-enhanced photochemically- induced fluorescence (MEPIF) was developed for the simultaneous determination of synthetic binary mixtures of four sulfonylurea herbicides in aqueous micellar solutions, and applied to tap water analysis. Because of their similar features, the MEPIF emission spectra of these herbicides were found to severely overlap in the whole wavelength region. After optimization of the calibration matrix, the PLS-1-MEPIF method was applied to the resolution of chlorsulfuron/metsulfuron methyl and sulfometuron methyl/3-rimsulfuron binary mixtures. The analytical results obtained by the PLS-1-MEPIF method were presented and compared to those of the first-derivative PIF one. An application of the PLS-1-MEPIF method to the quantitative analysis of Paris tap water samples spiked with the herbicide binary mixtures led to recovery values ranging between 63 and 118 %, depending on the mixture.
References
W. Lindberg, J.-A Persson, S. Wold, Partial least-squares method for spectrofluorimetric analysis of mixtures of humic acid and lignin sulfonate, Anal. Chem. 55, 643– 648 (1983).
K. R. Beebe, B. R. Kowalski, An introduction to multivariate calibration and analysis, Anal. Chem. 59, 1007A– 1017A (1987).
a) D. M. Haaland, E. V. Thomas, Partial least-squares methods for spectral analyses. 1. Relation to other quantitative calibration methods and the extraction of qualitative information, Anal. Chem. 60, 1193–1202 (1988). b) E. V. Thomas, D. M. Haaland, Comparison of multivariate calibration methods for quantitative spectral analysis, Anal. Chem. 62, 1091–1099 (1990).
A. Espinosa-Mansilla, A. Muñoz de la Peña, F. Salinas, A. Zamora, Simultaneous determination of pesticides by multivariate spectral analysis and derivative spectrophotometry, Anal. Chim. Acta 258, 47–53 (1992).
M. Sanchez-Peña, A. Muñoz de la Peña, F. Salinas, M.C. Mahedero, J.-J. Aaron, Determination of binary mixtures of sulfonamides by photochemically induced fluorescence using partial least squares multivariate calibration, Analyst 119, 1177–1181 (1994).
M. Martinez-Galera, J. L. Martinez-Vidal, A. Garrido- Frenich, P. Parrilla-Vasquez, Multicomponent determination of atrazine, diuron and chlorpyrifos in groundwaters and soils by spectrophotometry using multivariate calibration Analyst 119, 1189–1194 (1994).
R. Corbella-Teña, M. A. Rodriguez-Delgado, M. J. Sanchez, F. Garcia-Montelongo, Comparative study of the ratio spectra derivative and partial least squares methods applied to the simultaneous determination of atrazine and ametryn in ground waters, Analyst 121, 459–463 (1996).
I. Eide, H. G. Johnsen, Mixture design and multivariate analysis in mixture research, Environ. Health Perspect. Supl. 106, 1373–1376 (1998).
K. Kargosha, S. H. Ahmadi, A. Ghassempour and M. R. Arshadi, Simultaneous determination of pesticide naptalam and its metabolites in natural water by Fourier transform infrared spectrometry, Analyst 124, 367 (1999).
A. Garrido-Frenich, J. L. Martinez-Vidal, M. Martinez- Galera, Use of the cross-section technique linked with multivariate calibration methods to resolve complex pesticides mixtures Anal. Chem. 71, 4844–4850 (1999).
P. Parrilla-Vasquez, M. Martinez-Galera, A. Garrido- Frenich, J.L. Martinez-Vidal, Comparison of calibration methods with and without feature selection for the analysis of HPLC data, Anal. Sci. 16, 49–55 (2000).
A. D. Vidal, P. O. Barales, A. M. Diaz, Environmental water samples analysis of pesticides by means of chemometrics combined with fluorimetric multioptosensing, J. Fluorescence 17, 271–277 (2007).
E.M. Almansa-Lopez, A.M. Garcia-Campana, J.J. Aaron, L. Cuadros-Rodriguez, Micellar-enhanced photochemically induced fluorescence determination of chlorophenoxyacid herbicide mixtures using multivariate calibration, Luminescence 17, 217–219 (2002).
H. M. Brown, Mode of action, crop selectivity, and soil relations of the sulfonylurea herbicides, Pestic. Sci. 29, 263–281 (1990).
J. V. Hay, Chemistry of sulfonylurea herbicides, Pestic. Sci. 29, 247–261 (1990).
A. Coly, J.-J. Aaron, Photochemically-induced fluorescence determination of sulfonylurea herbicides using micellar media, Talanta 49, 107–117 (1999).
A. Coly, J.-J. Aaron, Sensitive and rapid flow injection analysis of sulfonylurea herbicides in waters with micellar- enhanced photochemically induced fluorescence detection, Anal. Chim. Acta 392, 255–264 (1999).
A. Coly, J.-J. Aaron, Simultaneous determination of binary mixtures of sulfonylurea herbicides in water by firstderivative photochemically induced spectrofluorimetry, J. AOAC Int. 84, 1745–1750 (2001).
Downloads
Published
How to Cite
Issue
Section
License
The authors agree to the following licence: Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)
- Share — copy and redistribute the material in any medium or format
- Adapt — remix, transform, and build upon the material
- for any purpose, even commercially.
Under the following terms:
Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- NonCommercial — You may not use the material for commercial purposes.