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Diclofenac analysis in natural waters using UV-visible absorption spectrometric method

Authors

  • Jean-Marie Bakhoum
  • Olivier Mbaye
  • Jean-Pierre Bakhoum University of Dakar, Senegal
  • Mame Diabou Gaye-Seye Laboratoire de Photochimie et d’Analyse, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Sénégal
  • Clément Trellu Laboratoire Géomatériaux et Environnement, Université Gustave Eiffel, Marne-la-Vallée, France
  • Coly Atanasse
  • Jean-Jacques Aaron Paris-Est Marne-la-Vallee University, Paris

DOI:

https://doi.org/10.20450/mjcce.2023.2750

Keywords:

non-steroidal anti-inflammatory drugs (NSAIDs); diclofenac; UV -VIS absorption spectrometry; environment.

Abstract

In this work, we developed an UV-visible (UV-VIS) absorption spectrometric method for the quantification of sodium diclofenac in natural waters. Several UV-VIS absorption method parameters were optimized. The maximum absorption wavelength was comprised between 276 and 292 nm, depending on the solvent, with molar absorption coefficients greater than 104 L mol-1 cm-1. The linearity of the UV-VIS calibration curves extended over one to three orders of magnitude, with correlation coefficients (R2) very close to unity. The low relative standard deviation (RSD)  values indicated a good reproducibility of the measurements. Analytical applications to natural waters yielded satisfactory results with average recovery rates between 94.7 and 99.1%.  

Author Biographies

Jean-Marie Bakhoum

Dept of Chemistry, graduate student

Olivier Mbaye

Dept. Chemistry, postdoc

Jean-Pierre Bakhoum, University of Dakar, Senegal

Department of Chemistry, Graduate Student 

Mame Diabou Gaye-Seye, Laboratoire de Photochimie et d’Analyse, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Sénégal

Professor

Coly Atanasse

Professor

Jean-Jacques Aaron, Paris-Est Marne-la-Vallee University, Paris

Laboratory Geomateriaux and Environment

Full Professor (Emeritus)

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Published

2023-11-29

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How to Cite

Bakhoum, J.-M., Mbaye, O., Bakhoum, J.-P., Gaye-Seye, M. D., Trellu, C., Atanasse, C., & Aaron, J.-J. (2023). Diclofenac analysis in natural waters using UV-visible absorption spectrometric method. Macedonian Journal of Chemistry and Chemical Engineering, 42(2). https://doi.org/10.20450/mjcce.2023.2750

Issue

Vol. 42 No. 2 (2023)

Section

Analytical Chemistry

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Copyright (c) 2023 Jean-Marie Bakhoum, Olivier Mbaye, Jean-Pierre Bakhoum, Mame Diabou Gaye-Seye, Clément Trellu, Coly Atanasse, Jean-Jacques Aaron

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